Exploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages

TitleExploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages
Publication TypeJournal Article
Year of Publication2017
AuthorsMadhu, S, Rashmi, EV, Gonnade, RGhanshyam, Sanjayan, GJ
JournalNew Journal of Chemistry
Volume17
Issue41
Pagination8721-8724
Date PublishedJUL
Type of ArticleArticle
AbstractUsing the gem-dimethyl effect as a platform, a variety of organic [2+2] macrocycles and [2+3] cofacial cages was obtained in high yields. Imine-based macrocyclization could be performed even at high concentrations (0.5 to 1.0 M), via instant mixing of aldehydes and amines.
DOI10.1039/C7NJ02069D
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.269
Divison category: 
Center for Material Characterization (CMC)
Organic Chemistry

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