Exploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages
Title | Exploring the gem-dimethyl effect in the formation of imine-based macrocycles and cages |
Publication Type | Journal Article |
Year of Publication | 2017 |
Authors | Madhu, S, Rashmi, EV, Gonnade, RGhanshyam, Sanjayan, GJ |
Journal | New Journal of Chemistry |
Volume | 17 |
Issue | 41 |
Pagination | 8721-8724 |
Date Published | JUL |
Type of Article | Article |
Abstract | Using the gem-dimethyl effect as a platform, a variety of organic [2+2] macrocycles and [2+3] cofacial cages was obtained in high yields. Imine-based macrocyclization could be performed even at high concentrations (0.5 to 1.0 M), via instant mixing of aldehydes and amines. |
DOI | 10.1039/C7NJ02069D |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 3.269 |
Divison category:
Center for Material Characterization (CMC)
Organic Chemistry
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