Exploiting the dual role of ethynylbenziodoxolones in gold-catalyzed C(sp)-C(sp) cross-coupling reactions
| Title | Exploiting the dual role of ethynylbenziodoxolones in gold-catalyzed C(sp)-C(sp) cross-coupling reactions |
| Publication Type | Journal Article |
| Year of Publication | 2017 |
| Authors | Banerjee, S, Patil, NT |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue | 56 |
| Pagination | 7937-7940 |
| Date Published | JUL |
| Type of Article | Article |
| Abstract | Reported herein is the gold-catalyzed alkynylation of terminal alkynes using ethynylbenziodoxolones (EBXs), where EBXs serve a dual role as oxidants as well as alkyne transfer agents to access unsymmetrical 1,3-diynes. Hence, the catalytic system requires no external oxidants and is compatible with a broad range of substrates, including those with polar functional groups such as NH, OHand B(OH)(2). |
| DOI | 10.1039/c7cc04283c |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.567 |
Divison category:
Organic Chemistry