Enhanced DSSC performance with high surface area thin anatase TiO2 nanoleaves
| Title | Enhanced DSSC performance with high surface area thin anatase TiO2 nanoleaves |
| Publication Type | Journal Article |
| Year of Publication | 2011 |
| Authors | Dhas, VV, Muduli, S, Agarkar, SA, Rana, A, Hannoyer, B, Banerjee, R, Ogale, SB |
| Journal | Solar Energy |
| Volume | 85 |
| Issue | 6 |
| Pagination | 1213-1219 |
| Date Published | JUN |
| Type of Article | Article |
| ISSN | 0038-092X |
| Keywords | Dye-sensitized solar cells, Electrochemical impedance spectroscopy, hydrothermal |
| Abstract | Thin anatase TiO2 nanoleaves (NLs) with high surface area (similar to 93 m(2)/g) are synthesized by hydrothermal route and dye-sensitized solar cells (DSSC) made using such NLs are compared with those made with hydro-thermally synthesized TiO2 nanoparticles and the Degussa P25 powder. The NLs-based DSSCs show increment of 16% and 24% in the total conversion efficiency over the cells made with NPs and P25 respectively. Interestingly, the highest increment in the conversion efficiency (similar to 35%) is achieved for cells made using a 50:50 (wt/wt) mixture of NLs and NPs. In this case the dye loading is found to be >50% higher than the case of NP films. Moreover the DC resistance of diffusion of I-3(-) in electrolyte (as revealed by the electrochemical impedance spectroscopy) is substantially lower than the NP film case, other cell parameters being nominally comparable. (C) 2011 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.solener.2011.02.029 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.69 |
