Enantiospecific route to (+)-(1R, 3S)-cis-chrysanthemic acid from (-)-D-pantolactone(1)
| Title | Enantiospecific route to (+)-(1R, 3S)-cis-chrysanthemic acid from (-)-D-pantolactone(1) |
| Publication Type | Journal Article |
| Year of Publication | 2011 |
| Authors | Hajare, AK, Datrange, LS, Murthy, YLN, Bhuniya, D, D. Reddy, S |
| Journal | Synthesis-Stuttgart |
| Issue | 7 |
| Pagination | 1067-1070 |
| Date Published | APR |
| ISSN | 0039-7881 |
| Keywords | alkenes, Metathesis, ring closure, stereoselective synthesis, Wittig reaction |
| Abstract | In this paper, a novel route for the synthesis of (+)-(1R,3S)-cis-chrysanthemic acid is described. The use of readily available (-)-D-pantolactone as a starting point, application of ring-closing metathesis to form the cyclopentene intermediate, and Haller-Bauer/Grob-type fragmentation to form the target compound are the highlights of the present synthesis. |
| DOI | 10.1055/s-0030-1258451 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.466 |
Divison category:
Organic Chemistry