Efficient synthesis of O-aryloxime ethers by copper fiuorapatite catalyzed cross-coupling of aryloximes with arylboronic acids

TitleEfficient synthesis of O-aryloxime ethers by copper fiuorapatite catalyzed cross-coupling of aryloximes with arylboronic acids
Publication TypeJournal Article
Year of Publication2014
AuthorsMulla, SAbdul Rash, Chavan, SS, Inamdar, SM, Pathari, MY, Shaikh, TMY
JournalTetrahedron Letters
Volume55
Issue38
Pagination5327-5332
Date PublishedSEP
Type of ArticleArticle
ISSN0040-4039
KeywordsArylboronic acid, Aryloxime, Copper fluorapatite, O-Aryloxime ethers
Abstract

A novel, highly efficient, and mild protocol has been developed for the synthesis of O-aryloxime ethers in good to excellent yields at ambient reaction conditions. This is the first report in which =N-O-Ar linkage was achieved with ecofriendly, recyclable, heterogeneous copper fluorapatite (CuFAP) catalyst via C-O cross coupling of aryloxime with arylboronic acid in the presence of Cs2CO3 as base and methanol as solvent. (C) 2014 Elsevier Ltd. All rights reserved.

DOI10.1016/j.tetlet.2014.07.056
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)2.68
Divison category: 
Chemical Engineering & Process Development
Organic Chemistry