Efficient synthesis of 9-aryldihydrophenanthrenes by a cascade reaction involving arynes and styrenes
| Title | Efficient synthesis of 9-aryldihydrophenanthrenes by a cascade reaction involving arynes and styrenes |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Bhojgude, SSuresh, Bhunia, A, Gonnade, RG, Biju, AT |
| Journal | Organic Letters |
| Volume | 16 |
| Issue | 3 |
| Pagination | 676-679 |
| Date Published | FEB |
| ISSN | 1523-7060 |
| Abstract | A mild, general, and transition-metal-free protocol for the synthesis of 9,10-dihydrophenanthrenes is reported. The aryne generated by the fluoride-induced,1,2-elimination of 2-(trimethylsilyl)aryl triflates undergoes an efficient cascade reaction initiated by the Diels-Alder reaction with the differently substituted styrenes leading to the formation of 9-aryl-9,10-dihydrophenanthrene derivatives in moderate to good yields. |
| DOI | 10.1021/ol4033094 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 7.03 |
Divison category:
Center for Material Characterization (CMC)
Organic Chemistry