Efficient, solvent-free method for the chemoselective synthesis of acylals from aldehydes and their deprotection catalyzed by silica sulfuric acid as a reusable solid acid catalyst
| Title | Efficient, solvent-free method for the chemoselective synthesis of acylals from aldehydes and their deprotection catalyzed by silica sulfuric acid as a reusable solid acid catalyst |
| Publication Type | Journal Article |
| Year of Publication | 2006 |
| Authors | Desai, UV, Thopate, TS, Pore, DM, Wadgaonkar, PP |
| Journal | Catalysis Communications |
| Volume | 7 |
| Issue | 7 |
| Pagination | 508-511 |
| Date Published | JUL |
| Type of Article | Article |
| ISSN | 1566-7367 |
| Keywords | Acylals, aldehydes, Chemoselective, protection and deprotection silica sulfuric acid |
| Abstract | An efficient method has been developed for the chemoselective synthesis of acylals from aldehydes and acetic anhydride in the presence of silica sulfuric acid as a reusable solid acid catalyst under solvent-free conditions. Ketones are found to remain unaffected under the reaction conditions. The deprotection of acylals has also been achieved using SSA in methanol medium. (c) 2006 Elsevier B.V. All rights reserved. |
| DOI | 10.1016/j.catcom.2005.12.028 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.389 |
Divison category:
Polymer Science & Engineering