Efficient robust fluorite CeZrO4-delta oxide catalyst for the eco-benign synthesis of styrene

TitleEfficient robust fluorite CeZrO4-delta oxide catalyst for the eco-benign synthesis of styrene
Publication TypeJournal Article
Year of Publication2015
AuthorsPeriyasamy, K, Aswathy, VT, Kumar, VAshok, Manikandan, M, Shukla, R, Tyagi, AK, Raja, T
JournalRSC Advances
Volume5
Issue5
Pagination3619-3626
Date PublishedDEC
ISSN2046-2069
Abstract

In this work, we have reported CeO2, ZrO2, physically mixed (PH)-CeO2/ZrO2 and fluorite CeZrO4-delta oxides and their catalytic activities for the oxidative dehydrogenation (ODH) of ethyl benzene (EB) to styrene (ST) using molecular oxygen, air and carbon dioxide as oxidants. The catalysts were prepared by a gel-combustion method followed by calcination at 600 degrees C for 6 h and subjected to catalytic activity measurements. All the catalysts were characterized and studied by various physicochemical methods. The reaction parameters were varied systematically such as different catalysts, oxidants, temperatures, EB flow and oxidant flow. CeZrO4-delta accounted for a 47% styrene yield for 72 h without any significant deactivation under optimized reaction conditions. A thorough analysis of the spent catalysts demonstrated the robustness of the catalyst for this reaction under different oxidants and reaction conditions. Pristine CeO2 deactivated easily and the activity decreased with time on stream of the reaction.

DOI10.1039/c4ra12355g
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)3.289
Divison category: 
Catalysis and Inorganic Chemistry