Efficient heterogeneous catalytic system for chemoselective hydrogenation of unsaturated ketones in aqueous medium
| Title | Efficient heterogeneous catalytic system for chemoselective hydrogenation of unsaturated ketones in aqueous medium |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Deshmukh, AA, Kinage, AK, Kumar, R, Meijboom, R |
| Journal | Polyhedron |
| Volume | 29 |
| Issue | 17 |
| Pagination | 3262-3268 |
| Date Published | NOV |
| ISSN | 0277-5387 |
| Keywords | 1 10 Phenanthroline, alpha beta Unsaturated ketone, Chemoselective hydrogenation, mesoporous materials, ruthenium |
| Abstract | A highly chemoselective and green heterogeneous catalytic system of immobilized Ru(II)-phenanthroline complexes on amino functionalised MCM-41 material for the chemoselective hydrogenation of unsaturated ketones to unsaturated alcohols is demonstrated using water as a solvent The XRD and FTIR spectra show the highly ordered hexagonal nature of the MCM-41 even after encapsulation of the ruthenium complex The complex retains its configuration after anchoring as was confirmed by FTIR and UV-Vis analysis The detailed reaction parametric effect was studied for the hydrogenation of 3 methylpent-3-en-2-one to achieve complete conversion up to >99% chemoselectivity of 3-methylpent-3-en-2 ol The anchored heterogeneous catalysts were recycled effectively and reused five times with marginal changes in activity and selectivity The use of water as a solvent not only afforded high activity for the hydroge nation reaction compared to organic solvents but also afforded a green process Crown Copyright (C) 2010 Published by Elsevier Ltd All rights reserved |
| DOI | 10.1016/j.poly.2010.09.006 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.033 |