Direct access to N-alkylated amines and imines via acceptorless dehydrogenative coupling catalyzed by a cobalt(ii)-NNN pincer complex

TitleDirect access to N-alkylated amines and imines via acceptorless dehydrogenative coupling catalyzed by a cobalt(ii)-NNN pincer complex
Publication TypeJournal Article
Year of Publication2018
AuthorsMidya, SP, Pitchaimani, J, Landge, VG, Madhu, V, Balaraman, E
JournalCatalysis Science & Technology
Volume8
Issue14
Pagination3469-3473
Date PublishedJUL
ISSN2044-4753
Abstract

A simple, phosphine-free Co(ii)-NNN pincer complex catalyzed direct N-alkylation of anilines with alcohols via hydrogen auto-transfer (HA) and selective acceptorless dehydrogenative coupling (ADC) of benzylamines with alcohols affording imines with the liberation of molecular hydrogen and water is reported.

DOI10.1039/c8cy00859k
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)5.773
Divison category: 
Organic Chemistry

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