Dibutyltin oxide catalyzed aminolysis of oxalate to carbamate, oxamate and derivatives of imidazolidine trione

TitleDibutyltin oxide catalyzed aminolysis of oxalate to carbamate, oxamate and derivatives of imidazolidine trione
Publication TypeJournal Article
Year of Publication2010
AuthorsKunde, LB, Kalyani, VS, Gupte, SP
JournalApplied Organometallic Chemistry
Volume24
Issue5
Pagination402-407
Date PublishedMAY
ISSN0268-2605
KeywordsAminolysis, carbamate, derivative of imidazolidine trione, oxalate, oxamate, transfunctionalyzation, Urea
Abstract

Catalytic aminolysis of oxalates by simple and substituted ureas has been shown to give carbamates, oxamates and derivatives of imidazolidine trione. Various substituted ureas and oxalates were screened to verify the applicability of the protocol. The role of dibutyltin oxide as catalyst, effect of solvent and reaction conditions on product distribution pattern has been discussed. Copyright (C) 2010 John Wiley & Sons, Ltd.

DOI10.1002/aoc.1629
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.062
Divison category: 
Chemical Engineering & Process Development