Densities and heat capacities of the ammonia plus water plus NaOH and ammonia plus water plus KOH solutions

TitleDensities and heat capacities of the ammonia plus water plus NaOH and ammonia plus water plus KOH solutions
Publication TypeJournal Article
Year of Publication2006
AuthorsSalavera, D, Libotean, S, Patil, KR, Esteve, X, Coronas, A
JournalJournal of Chemical and Engineering Data
Volume51
Issue3
Pagination1020-1025
Date PublishedMAY
Type of ArticleArticle
ISSN0021-9568
Abstract

Ammonia + water + sodium hydroxide and ammonia + water + potassium hydroxide mixtures were chosen as potential candidates for absorption chillers driven by low-temperature heat sources. Heat capacity and density were studied between (293.15 and 353.15) K at a constant pressure of 1.8 MPa for these solutions using a heat flux Calvet-type calorimeter and a vibrating-tube densimeter, respectively. Measured data were well-correlated with temperature and composition using simple polynomial equations. The relative deviations between the experimental and calculated values in the density and heat capacity measurements were 0.20 % and 0.49 % for NH3 + H2O + NaOH solutions and 0.10 % and 0.36 % for NH3 + H2O + KOH solutions, respectively. Also, two density prediction methods were checked using the experimental data. Previously, it was necessary to measure the density of ammonia and hydroxide aqueous solutions in similar conditions. The results showed that both methods are suitable for predicting the density of these solutions.

DOI10.1021/je050512z
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)1.835
Divison category: 
Center for Material Characterization (CMC)