Cu(OTf)(2)-catalyzed alpha-halogenation of ketones with 1,3-dichloro-5,5 `-dimethylhydantoin and N-bromosuccinimide
Title | Cu(OTf)(2)-catalyzed alpha-halogenation of ketones with 1,3-dichloro-5,5 `-dimethylhydantoin and N-bromosuccinimide |
Publication Type | Journal Article |
Year of Publication | 2009 |
Authors | Jagdale, AR, Chouthaiwale, PV, Sudalai, A |
Journal | Indian Journal of Chemistry Section B-Organic Chemistry including Medicinal Chemistry |
Volume | 48 |
Issue | 10 |
Pagination | 1424-1430 |
Date Published | OCT |
ISSN | 0376-4699 |
Keywords | Bromination, Catalyst, chlorination, copper (II), Ketone, Lewis acid |
Abstract | Copper(II) triflate catalyses efficiently the alpha-halogentation of aryl or alkyl ketones with 1,3-dichloro-5,5'-dimethyl-hydantoin and N-bromosaccinimde to give the corresponding alpha,alpha-dichloroketones and alpha-bromoketones in high yield with excellent product selectivity. |
Type of Journal (Indian or Foreign) | Indian |
Impact Factor (IF) | 0.562 |
Divison category:
Chemical Engineering & Process Development