Cross-coupling reactions of aryldiazonium salts with allylsilanes under merged gold/visible-light photoredox catalysis

TitleCross-coupling reactions of aryldiazonium salts with allylsilanes under merged gold/visible-light photoredox catalysis
Publication TypeJournal Article
Year of Publication2017
AuthorsAkram, MO, Mali, PS, Patil, NT
JournalOrganic Letters
Volume19
Issue12
Pagination3075-3078
Date PublishedJUN
Type of ArticleArticle
AbstractA method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.
DOI10.1021/acs.orglett.7b01148
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)6.732
Divison category: 
Organic Chemistry

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