Copper(I) bromide-catalyzed carbonylative coupling of aryl halides with phenols, alcohols and amines using sodium cyanide as C-1 source: a synthesis of carboxylic acid derivatives
Title | Copper(I) bromide-catalyzed carbonylative coupling of aryl halides with phenols, alcohols and amines using sodium cyanide as C-1 source: a synthesis of carboxylic acid derivatives |
Publication Type | Journal Article |
Year of Publication | 2014 |
Authors | Prasad, PK, Sudalai, A |
Journal | Advanced Synthesis & Catalysis |
Volume | 356 |
Issue | 10 |
Pagination | 2231-2238 |
Date Published | JUL |
ISSN | 1615-4150 |
Keywords | anhydrides, C-1 building blocks, isochroman-1-ones, lactams, lactones |
Abstract | A new ``carbon monoxide-free'' synthesis of carboxylate derivatives via carbonylative coupling of aryl bromides with phenols, alcohols, amines and acids in the presence of copper(I) bromide as catalyst and sodium cyanide in a stoichiometric amount has been developed. Its intramolecular version provides for the preparation of lactones (e.g., isochroman-1-ones and isobenzfuranones), imides, anhydrides and lactams in excellent yields (73-96%). |
DOI | 10.1002/adsc.201301155 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 6.453 |
Divison category:
Chemical Engineering & Process Development