Continuous flow synthesis of metal nanowires: protocols, engineering aspects of scale-up and applications

TitleContinuous flow synthesis of metal nanowires: protocols, engineering aspects of scale-up and applications
Publication TypeJournal Article
Year of Publication2025
AuthorsSonawane, JR, Jundale, R, Kulkarni, AA
JournalMaterials Horizons
Volume12
Issue2
Pagination364-400
Date PublishedJAN
Type of ArticleReview
ISSN2051-6347
Abstract

This review comprehensively covers the translation from batch to continuous flow synthesis of metal nanowires (i.e., silver, copper, gold, and platinum nanowires) and their diverse applications across various sectors. Metal nanowires have attracted significant attention owing to their versatility and feasibility for large-scale synthesis. The efficacy of flow chemistry in nanomaterial synthesis has been extensively demonstrated over the past few decades. Continuous flow synthesis offers scalability, high throughput screening, and robust and reproducible synthesis procedures, making it a promising technology. Silver nanowires, widely used in flexible electronics, transparent conductive films, and sensors, have benefited from advancements in continuous flow synthesis aimed at achieving high aspect ratios and uniform diameters, though challenges in preventing agglomeration during large-scale production remain. Copper nanowires, considered as a cost-effective alternative to silver nanowires for conductive materials, have benefited from continuous flow synthesis methods that minimize oxidation and enhance stability, yet scaling up these processes requires precise control of reducing environments and copper ion concentration. A critical evaluation of various metal nanowire ink formulations is conducted, aiming to identify formulations that exhibit superior properties with lower metal solid content. This study delves into the intricacies of continuous flow synthesis methods for metal nanowires, emphasizing the exploration of engineering considerations essential for the design of continuous flow reactors. Furthermore, challenges associated with large-scale synthesis are addressed, highlighting the process-related issues. This review comprehensively covers the translation from batch to continuous flow synthesis of metal nanowires (i.e., silver, copper, gold, and platinum nanowires) and their diverse applications across various sectors.

DOI10.1039/d4mh00781f
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

12.2

Divison category: 
Chemical Engineering & Process Development
Database: 
Web of Science (WoS)

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