Combined experimental and theoretical study of the structural, electronic and vibrational properties of bulk and few-layer Td-WTe2

TitleCombined experimental and theoretical study of the structural, electronic and vibrational properties of bulk and few-layer Td-WTe2
Publication TypeJournal Article
Year of Publication2015
AuthorsJana, MK, Singh, A, Late, DJ, Rajamathi, CR, Biswas, K, Felser, C, Waghmare, UV, Rao, CNR
JournalJournal of Physics-Condensed Matter
Volume27
Issue28
Pagination285401
Date PublishedJUL
ISSN0953-8984
KeywordsRaman spectroscopy, Td-structure, tungsten ditelluride
Abstract

The recent discovery of non-saturating giant positive magnetoresistance has aroused much interest in Td-WTe2. We have investigated structural, electronic and vibrational properties of bulk and few-layer Td-WTe2 experimentally and theoretically. Spin-orbit coupling is found to govern the semi-metallic character of Td-WTe2 and its structural link with the metallic 1 T form provides an understanding of its structural stability. There is a metal-to-insulator switch-over in the electrical conductivity and a change in the sign of the Seebeck coefficient around 373 K. Lattice vibrations of Td-WTe2 have been analyzed using first-principles calculations. Out of the 33 possible zone-center Raman active modes, five distinct Raman bands are observed around 112, 118, 134, 165 and 212 cm(-1) in bulk Td-WTe2. Based on symmetry analysis and calculated Raman tensors, we assign the intense bands at 165 cm(-1) and 212 cm(-1) to the A(1)' and A(1)'' modes, respectively. Most of the Raman bands stiffen with decreasing thickness, and the ratio of the integrated intensities of the A(1)'' to A(1)' bands decreases in the few-layer sample, while all the bands soften in both the bulk and few-layer samples with increasing temperature.

DOI10.1088/0953-8984/27/28/285401
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)2.209
Divison category: 
Physical and Materials Chemistry