Clay entrapped Cu(OH)(x) as an efficient heterogeneous catalyst for ipso-hydroxylation of arylboronic acids

TitleClay entrapped Cu(OH)(x) as an efficient heterogeneous catalyst for ipso-hydroxylation of arylboronic acids
Publication TypeJournal Article
Year of Publication2013
AuthorsDar, BAhmad, Bhatti, P, Singh, AP, Lazar, A, Sharma, PR, Sharma, M, Singh, B
JournalApplied Catalysis A-General
Volume466
Pagination60-67
Date PublishedSEP
ISSN0926-860X
Keywordsclay, Copper, heterogeneous catalysis, Phenols, Water chemistry
Abstract

A remarkably active, selective and stable montmorilonite-KSF entrapped Cu(OH)(x) catalyst, has been prepared for the ipso-hydroxylation of arylboronic acids under ambient conditions without requirement of any ligand or base. This catalyst shows excellent reusability without leaching and any significant loss in catalytic activity. The catalyst was characterized using, XRD, SEM, TPR, IR, XPS and BET surface area measurement techniques. (C) 2013 Elsevier B.V. All rights reserved.

DOI10.1016/j.apcata.2013.06.051
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.674
Divison category: 
Catalysis and Inorganic Chemistry