Chiral Mn(III) salen complex immobilized onto ionic liquid modified mesoporous silica for oxidative kinetic resolution of secondary alcohols
| Title | Chiral Mn(III) salen complex immobilized onto ionic liquid modified mesoporous silica for oxidative kinetic resolution of secondary alcohols |
| Publication Type | Journal Article |
| Year of Publication | 2008 |
| Authors | Sahoo, S, Kumar, P, Lefebvre, F, Halligudi, SB |
| Journal | Tetrahedron Letters |
| Volume | 49 |
| Issue | 33 |
| Pagination | 4865-4868 |
| Date Published | AUG |
| Type of Article | Article |
| ISSN | 0040-4039 |
| Keywords | Mesoporous silica SBA-15, Mn(III) salen, Oxidative kinetic resolution, Secondary alcohol, Supported ionic liquid |
| Abstract | A supported ionic liquid strategy has been applied for the immobilization of a chiral Mn(III) salen complex onto ionic liquid modified mesoporous silica SBA-15. The immobilized catalyst demonstrated high enantioselectivity and activity in the oxidative kinetic resolution of secondary alcohols, and could be recycled five times without obvious loss of activity. (C) 2008 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.tetlet.2008.06.014 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.347 |
Divison category:
Catalysis and Inorganic Chemistry