C=C insertion over N=C=O of allyl isocyanate into the Ge-Si bond of a germylene
| Title | C=C insertion over N=C=O of allyl isocyanate into the Ge-Si bond of a germylene |
| Publication Type | Journal Article |
| Year of Publication | 2025 |
| Authors | Ajithkumar, VS, Khilari, N, Ghanwat, PB, Koley, D, Sen, SS |
| Journal | European Journal of Inorganic Chemistry |
| Volume | 28 |
| Issue | 26 |
| Date Published | SEP |
| Type of Article | Article |
| ISSN | 1434-1948 |
| Keywords | Cyclotrimerization, Density functional theory, Germylene, Insertion, isocyanates |
| Abstract | Two isocyanates are reacted with the germylene, PhC(NtBu)(2)Ge-Si(SiMe3)(3) (1). Phenyl isocyanate undergoes catalytic cyclotrimerization with 1 leading to 1,3,5-triphenyl isocyanurate (2), while allyl isocyanate undergoes both cyclotrimerization and the C=C bond insertion between the Ge-Si bond. The constitution of 3 is determined by single-crystal X-ray studies. The contrasting reactivity pattern is explained by comprehensive density functional theory studies. |
| DOI | 10.1002/ejic.202500305 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2 |
Divison category:
Catalysis and Inorganic Chemistry
Database:
Web of Science (WoS)
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