Catalytic hydrogenation of cinnamic acid and salicylic acid
Title | Catalytic hydrogenation of cinnamic acid and salicylic acid |
Publication Type | Journal Article |
Year of Publication | 2020 |
Authors | Shinde, S, Deshpande, RM |
Journal | Asian Journal of Chemistry |
Volume | 32 |
Issue | 2 |
Pagination | 339-341 |
Date Published | JAN |
Type of Article | Article |
Abstract | Hydrogenation of cinnamic acid and salicylic acid was carried out using 5 %Ru/C, 5 % Pd/C and Ru-Sn/Al2O3 catalyst at 493 K and 6.89 MPa of hydrogen partial pressure. Ru-Sn/Al2O3 catalyst was found to be active for hydrogenation -COOH group to give cinnamyl alcohol. The selectivity to cinnamyl alcohol was low (15 %) as absolute inhibition of C=C bond hydrogenation in cinnamic acid is challenging. 5 %Pd/C catalyst was found to hydrogenate C=C bond and aromatic ring in cinnamic acid. 5 %Ru/C catalyst was found to be least selective catalyst as it hydrogenated C=C bond, aromatic ring and -COOH group in cinnamic acid. Hydrogenation of salicylic acid is not possible at 493 K as decarboxylation of salicylic acid occurs. |
DOI | 10.14233/ajchem.2020.22393 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 0.336 |
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