Catalyst-free regioselective [3+2] cycloadditions of alpha,beta-unsaturated N-arylnitrones with alkenes to access functionalized isoxazolidines: a DFT study
| Title | Catalyst-free regioselective [3+2] cycloadditions of alpha,beta-unsaturated N-arylnitrones with alkenes to access functionalized isoxazolidines: a DFT study |
| Publication Type | Journal Article |
| Year of Publication | 2020 |
| Authors | Ghosh, A, Mane, MV, Rode, HB, Patil, SA, Sridhar, B, Dateer, RB |
| Journal | Chemistry-An Asian Journal |
| Volume | 15 |
| Issue | 6 |
| Pagination | 899-903 |
| Date Published | MAR |
| Type of Article | Article |
| ISSN | 1861-4728 |
| Keywords | DFT study, isoxazolidines, metal and ligand free, nitrone cycloaddition, Regioselective |
| Abstract | The catalyst-free regioselective [3+2]-cycloaddition of alpha,beta-unsaturated N-arylnitrones with alkenes are developed. The series of synthetically important functionalized isoxazolidines are prepared in good to excellent yields by step economic pathway under ligand and transition-metal-free conditions. The regioselective cycloaddition pathway supported by control experiment and computational study. |
| DOI | 10.1002/asia.201901754, Early Access Date = FEB 2020 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.056 |
Divison category:
Physical and Materials Chemistry