Calcium oxide supported gold nanoparticles as catalysts for the selective epoxidation of styrene by t-butyl hydroperoxide

TitleCalcium oxide supported gold nanoparticles as catalysts for the selective epoxidation of styrene by t-butyl hydroperoxide
Publication TypeJournal Article
Year of Publication2014
AuthorsDumbre, DK, Choudhary, VR, Patil, NS, Uphade, BS, Bhargava, SKumar
JournalJournal of Colloid and Interface Science
Volume415
Pagination111-116
Date PublishedFEB
Type of ArticleArticle
ISSN0021-9797
KeywordsAu/CaO, Epoxidation of styrene, gold nanoparticles, Homogenous deposition precipitation method, Styrene oxide
Abstract

Gold nanoparticles are deposited on basic CaO supports as catalysts for the selective conversion of styrene into styrene oxide. Synthetic methods, gold loading and calcination temperatures are varied to permit an understanding of their influence on gold nanoparticle size, the presence of cationic gold species and the nature of interaction between the gold nanoparticles and the CaO support. Based on these studies, optimal conditions are designed to make the Au/CaO catalyst efficient for the selective epoxidation of styrene. (C) 2013 Elsevier Inc. All rights reserved.

DOI10.1016/j.jcis.2013.10.016
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.782
Divison category: 
Chemical Engineering & Process Development