Biosynthesized Co-doped TiO2 nanoparticles based anode for lithium-ion battery application and investigating the influence of dopant concentrations on its performance
| Title | Biosynthesized Co-doped TiO2 nanoparticles based anode for lithium-ion battery application and investigating the influence of dopant concentrations on its performance |
| Publication Type | Journal Article |
| Year of Publication | 2019 |
| Authors | Kashale, AA, Rasal, AS, Kamble, GP, Ingole, VH, Dwivedi, PK, Rajoba, SJ, Jadhav, LD, Ling, YC, Chang, JY, Ghule, AV |
| Journal | Composites Part B: Engineering |
| Volume | 167 |
| Pagination | 44-50 |
| Date Published | JUN |
| Type of Article | Article |
| Abstract | TiO2 is a good alternative anode material for lithium-ion battery application because of its incomparable high structural stability and safety during the charge/discharge cycles. However, the low intrinsic conductivity of TiO2 has been a limiting factor affecting its cycling and rate capability performance. Here in this work, we present Co-doped TiO2 nanoparticles based anode with good reversibility, cycling stability and rate capability performance for its envisaged application in lithium-ion battery. The Co-doped TiO2 nanoparticles with different Co concentrations (3%, 5%, and 7%) are synthesized using simple and economic biomediated green approach, wherein TiCl4 and Co precursors are allowed to react in Bengal gram bean extract containing biomolecules which act as natural capping agents to control the size of nanoparticles. Among the pure TiO2 and different Co-doped TiO2 samples, the 7% Co-doped TiO2 anode show the highest capacity of 167 mAh g−1 (88.3%) after 100 cycles at the 0.5C current density. The Co-doped TiO2 shows higher and stable coulombic efficiency up to 100 GCD cycles indicating good reversibility. Based on the results, it is expected that the Co-doped TiO2 nanoparticles might be contributing to the enhanced electronic conductivity providing an efficient pathway for fast electron transfer. |
| DOI | 10.1016/j.compositesb.2018.12.001 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.920 |
Divison category:
Physical and Materials Chemistry
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