Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

TitleBenz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance
Publication TypeJournal Article
Year of Publication2017
AuthorsYadav, S, Pahar, S, Sen, SS
JournalChemical Communications
Volume53
Issue33
Pagination4562-4564
Date PublishedAPR
Type of ArticleArticle
AbstractA benz-amidinato calcium compound, [PhC(NiPr)(2)Cal] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines.
DOI10.1039/c7cc02311a
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)6.290
Divison category: 
Catalysis and Inorganic Chemistry

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