Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance
Title | Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance |
Publication Type | Journal Article |
Year of Publication | 2017 |
Authors | Yadav, S, Pahar, S, Sen, SS |
Journal | Chemical Communications |
Volume | 53 |
Issue | 33 |
Pagination | 4562-4564 |
Date Published | APR |
Type of Article | Article |
Abstract | A benz-amidinato calcium compound, [PhC(NiPr)(2)Cal] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines. |
DOI | 10.1039/c7cc02311a |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 6.290 |
Divison category:
Catalysis and Inorganic Chemistry
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