2,5-dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [(bpy)(2)Ru(2)(mu-H2L)](n) (n=0,+,2+,3+,4+) and [(acac)(2)Ru(2)(mu-H2L)]
| Title | 2,5-dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [(bpy)(2)Ru(2)(mu-H2L)](n) (n=0,+,2+,3+,4+) and [(acac)(2)Ru(2)(mu-H2L)] |
| Publication Type | Journal Article |
| Year of Publication | 2005 |
| Authors | Kar, S, Sarkar, B, Ghumaan, S, Janardanan, D, van Slageren, J, Fiedler, J, Puranik, VG, Sunoj, RB, Kaim, W, Lahiri, GKumar |
| Journal | Chemistry - a European Journal |
| Volume | 11 |
| Issue | 17 |
| Pagination | 4901-4911 |
| Date Published | AUG |
| Type of Article | Article |
| ISSN | 0947-6539 |
| Keywords | bridging ligands, Density functional calculations, EPR spectroscopy, N, O ligands, ruthenium |
| Abstract | {The symmetrically dinuclear title compounds were isolated as diamagnetic [(bpy)(2)Ru(mu-H2L)Ru(bpy)(2)]- (ClO4)(2) (1-(ClO4)(2)) and as paramagnetic [(acac)(2)Ru(mu-H2L)Ru(acac)(2)] (2) complexes (bpy = 2,2'-bipyridine; acac(-) - |
| DOI | 10.1002/chem.2005.00202 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 5.771 |
Divison category:
Center for Material Characterization (CMC)
Physical and Materials Chemistry