Dual-functional LaFeO3 perovskites via auto-combustion and hydrothermal methods for gas sensing and photocatalytic dye degradation

TitleDual-functional LaFeO3 perovskites via auto-combustion and hydrothermal methods for gas sensing and photocatalytic dye degradation
Publication TypeJournal Article
Year of Publication2025
AuthorsPatil, SS, Shinde, KP, Patil, AP, Abbas, MAoun, Nadargi, JD, Mujawar, SH, Mulla, IS, Kim, KB, Suryavanshi, SS
JournalInorganic Chemistry Communications
Volume182
Pagination115493
Date PublishedDEC
Type of ArticleArticle
ISSN1387-7003
KeywordsDye degradation, Gas sensing, LaFeO3, Malachite Green, Perovskites
Abstract

Integrated environmental remediation is increasingly focused on the development of multifunctional materials capable of simultaneous detection of toxic gases and wastewater treatment. Present study aims to develop dual-functional LaFeO3 perovskites for gas sensing and photocatalytic dye degradation. The nanocrystalline powders of LaFeO3 were synthesized via two distinct methods; auto-combustion (A-LFO) and hydrothermal (H-LFO). Numerous characterization techniques (e.g. XRD, SEM, EDAX, BET, TEM, and XPS) were utilized in order to study the phase, morphology, surface area and elemental composition of A-LFO and H-LFO samples. Both samples were systematically evaluated for their potential in the gas sensing and photocatalytic degradation of malachite green (MG). In results, A-LFO exhibited superior performance in both applications, compared to the H-LFO. It shows similar to 90 % sensitivity for the acetone (500 ppm) at the operating temperature of 275 degrees C and achieved similar to 78 % degradation efficiency for malachite green (MG) dye (5 ppm) within 2 h irradiation of natural sunlight. Although, H-LFO presented comparatively lower performance, both materials demonstrated good selectivity, and stability highlighting their promise as a dual-functional environmental remediation agent. By exploring the performance of the synthesized materials in these dual applications, this research established a relationship between synthesis methods, material properties, and overall performance in environmental and industrial applications, by offering a sustainable and efficient solution to complex pollution challenges.

DOI10.1016/j.inoche.2025.115493
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

4.4

Divison category: 
Physical and Materials Chemistry
Database: 
Web of Science (WoS)

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