<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Wahid, M.</style></author><author><style face="normal" font="default" size="100%">Gawli, Y.</style></author><author><style face="normal" font="default" size="100%">Puthusseri, D.</style></author><author><style face="normal" font="default" size="100%">Kumar, A.</style></author><author><style face="normal" font="default" size="100%">Shelke, M. V.</style></author><author><style face="normal" font="default" size="100%">Ogale, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Nutty carbon: morphology replicating hard carbon from walnut shell for na ion battery anode</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Omega</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">Biological and Medicinal chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Biological materials</style></keyword><keyword><style  face="normal" font="default" size="100%">diffraction</style></keyword><keyword><style  face="normal" font="default" size="100%">Electric Properties</style></keyword><keyword><style  face="normal" font="default" size="100%">Electrode-electrolyte interface</style></keyword><keyword><style  face="normal" font="default" size="100%">spectra</style></keyword><keyword><style  face="normal" font="default" size="100%">Surface structure</style></keyword><keyword><style  face="normal" font="default" size="100%">Thermal properties</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">2</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;div id=&quot;absImg&quot; style=&quot;position: relative; margin: 0px; padding: 5px; border: 1px solid rgb(204, 204, 204); border-radius: 5px; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial; text-align: center; color: rgb(0, 0, 0); font-family: Helvetica, Arial, sans-serif; font-size: 14px;&quot;&gt;&lt;img alt=&quot;Abstract Image&quot; src=&quot;http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/acsodf/2017/acsodf.2017.2.issue-7/acsomega.7b00633/20170713/images/medium/ao-2017-00633k_0006.gif&quot; style=&quot;border: 0px; max-width: 100%;&quot;&gt;&lt;/div&gt;&lt;p class=&quot;articleBody_abstractText&quot; style=&quot;margin: 0px 0px 1.5em; line-height: 1.6em; padding: 0pt; width: 610px; word-wrap: break-word; color: rgb(0, 0, 0); font-family: Helvetica, Arial, sans-serif; font-size: 14px;&quot;&gt;Efficient Na ion intercalation/deintercalation in the semigraphitic lattice of a hard carbon derived from the walnut shell is demonstrated. High-temperature (1000 °C) pyrolysis of walnut shells under an inert atmosphere yields a hard carbon with a low surface area (59 m&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;2&lt;/span&gt;&amp;nbsp;g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;) and a large interplanar&amp;nbsp;&lt;i&gt;c&lt;/i&gt;&amp;nbsp;axis separation of 0.39–0.36 nm as compared to 0.32 nm for graphite, suitable for Na ion intercalation/deintercalation. A stable reversible capacity of 257 mAh g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;&amp;nbsp;is observed at a current density of 50 mA g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;&amp;nbsp;for such nutshell-derived carbon (NDC) with an impressive rate performance. No loss of electrochemical performance is observed for high current cycling (100 mA g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;&amp;nbsp;→ 2 A g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;&amp;nbsp;→ 100 mA g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;). Additionally, the NDC shows remarkably stable electrochemical performance up to 300 charge–discharge cycles at 100 mA g&lt;span style=&quot;vertical-align: 0.4em; font-size: 0.8em; line-height: 0.8em;&quot;&gt;–1&lt;/span&gt;&amp;nbsp;with a minimal drop in capacity.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">Not Available</style></custom4><section><style face="normal" font="default" size="100%">3601–3609</style></section></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Aiyappa, Harshitha Barike</style></author><author><style face="normal" font="default" size="100%">Bhange, Siddheshwar N.</style></author><author><style face="normal" font="default" size="100%">Sivasankaran, Vijitha P.</style></author><author><style face="normal" font="default" size="100%">Kurungot, Sreekumar</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Single cell fabrication towards the realistic evaluation of a CNT-strung ZIF-derived electrocatalyst as a cathode material in alkaline fuel cells and metal-air batteries</style></title><secondary-title><style face="normal" font="default" size="100%">ChemElectroChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">Carbon nanotubes</style></keyword><keyword><style  face="normal" font="default" size="100%">Composite materials</style></keyword><keyword><style  face="normal" font="default" size="100%">fuel cells</style></keyword><keyword><style  face="normal" font="default" size="100%">metal-organic frameworks</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">4</style></volume><pages><style face="normal" font="default" size="100%">2928-2933</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The development of an electrocatalyst possessing all the vital requisites of an ideal electrode material, such as high porosity, high conductivity, and high intrinsic electrochemical activity, holds a decisive key in determining the activity of the triplephase boundary in many energy devices like fuel cells and metal-air battery systems. In the present work, highly porous cobalt-based ZIFs are strung along the highly conducive CNT backbone by using a simple one-pot technique at room temperature, which is then utilized to derive a porous, corrosion-resistant, Co nanoparticle-embedded electrocatalyst. Herein, for the first time, the single cell performance of the Co-ZIF-67-derived electrocatalyst has been evaluated by fabricating membrane electrode assemblies of alkaline exchange membrane fuel cell (AEMFC) and zinc-air battery (ZAB) systems. A maximum power density of 296 mW/cm(2) (vs. 317 mW/cm(2) for 40 wt.% Pt/C) and 60 mW/cm(2) (vs. 64 mW/cm(2) for 40 wt.% Pt/C) in the single cells of ZAB and AEMFC systems, respectively, establishes the practical proficiency of the homemade electrocatalyst for cathode applications during realistic system-level validations.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">11</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.446</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Yadav, Poonam</style></author><author><style face="normal" font="default" size="100%">Sharma, Neha</style></author><author><style face="normal" font="default" size="100%">Patrike, Apurva</style></author><author><style face="normal" font="default" size="100%">Sabri, Ylias M.</style></author><author><style face="normal" font="default" size="100%">Jones, Lathe A.</style></author><author><style face="normal" font="default" size="100%">Shelke, V. Manjusha</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Electrochemical evaluation of the stability and capacity of r-GO-wrapped copper antimony chalcogenide anode for Li-ion battery</style></title><secondary-title><style face="normal" font="default" size="100%">ChemElectroChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">chalcogenides</style></keyword><keyword><style  face="normal" font="default" size="100%">Diffusion coefficient</style></keyword><keyword><style  face="normal" font="default" size="100%">lithium</style></keyword><keyword><style  face="normal" font="default" size="100%">Ternary sulfides</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">7</style></volume><pages><style face="normal" font="default" size="100%">3291-3300</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Poor cycling stability and capacity fade are primary concerns for next-generation anode materials for Li-ion batteries. In non-carbonaceous anode materials, alloying with Li leads to volume increase that affects practical applications, and increase in particle size, amorphization and reduced conductivity can all lead to a loss of performance. In this work, binary antimony sulfide (Sb2S3) and ternary copper antimony sulfide (CuSbS2) are synthesized by a convenient solvothermal process. These materials are used to study the Li-active/inactive concept, by incorporating Cu into Sb(2)S(3)forming CuSbS(2)wherein Cu is Li inactive whereas Sb is Li active. By direct comparison, we have shown that incorporating Cu into binary antimony sulfide (Sb2S3) resulting into ternary copper antimony sulfide (CuSbS2) addresses the problem of poor conductivity and capacity loss, as Cu provides conductivity leading to enhanced charge transfer and prevents Sb particle aggregation while charge-discharge by exhibiting spectator or diluent ion effect. The better performance of CuSbS(2)is associated with the better Li(+)ion diffusion in the CuSbS2(D=8.97x10(-15) cm(2) s(-1)) compared to Sb2S3(D=2.76x10(-15) cm(2) s(-1)) and lower series resistance of CuSbS2(R=4.70x10(5) omega) compared to Sb2S3(R=5.81x10(8) omega). We have also investigated the composite with the addition of rGO. The CuSbS2-rGO delivered a reversible capacity of 672 mAh g(-1)after 1000 cycles at 200 mA g(-1)which has shown best performance.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">15</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;4.154&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Patrike, Apurva</style></author><author><style face="normal" font="default" size="100%">Yadav, Poonam</style></author><author><style face="normal" font="default" size="100%">Shelke, Vilas</style></author><author><style face="normal" font="default" size="100%">Shelke, Manjusha</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Research progress and perspective on lithium/sodium metal anodes for next-generation rechargeable batteries</style></title><secondary-title><style face="normal" font="default" size="100%">ChemSusChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">anode</style></keyword><keyword><style  face="normal" font="default" size="100%">Batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">dendrite growth</style></keyword><keyword><style  face="normal" font="default" size="100%">Electrolytes</style></keyword><keyword><style  face="normal" font="default" size="100%">Energy storage</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">15</style></volume><pages><style face="normal" font="default" size="100%">e202200504</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	With the development of consumer electronic devices and electric vehicles, lithium-ion batteries (LIBs) are vital components for high energy storage with great impact on our modern life. However, LIBs still cannot meet all the essential demands of rapidly growing new industries. In pursuance of higher energy requirement, metal batteries (MBs) are the next-generation high-energy-density devices. Li/Na metals are considered as an ideal anode for high-energy batteries due to extremely high theoretical specific capacity (3860 and 1165 mAh g(-1) for Li and Na, respectively) and low electrochemical potential (-3.04 V for Li and -2.71 V for Na vs. standard hydrogen electrode). Unfortunately, uncontrolled dendrite growth, high reactivity, and infinite volume change induce severe safety concerns and poor cycle efficiency during their application. Consequently, MBs are far from commercialization stage. This Review represents a comprehensive overview of failure mechanism of lithium/sodium metal anode and its progress for rechargeable batteries through (i) electrolyte optimization, (ii) artificial solid-electrolyte interphase (SEI) layer formation, and (iii) nanoengineering at materials level in current collector, anode, and host. The challenges in current MBs research and potential applications of lithium/sodium metal anodes are also outlined and summarized.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">14</style></issue><work-type><style face="normal" font="default" size="100%">Review</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	9.140&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kumar, Viksit</style></author><author><style face="normal" font="default" size="100%">Javaregowda, Bharathkumar H.</style></author><author><style face="normal" font="default" size="100%">Devasia, George</style></author><author><style face="normal" font="default" size="100%">Narayanan, Aswini</style></author><author><style face="normal" font="default" size="100%">Krishnamurty, Sailaja</style></author><author><style face="normal" font="default" size="100%">Krishnamoorthy, Kothandam</style></author><author><style face="normal" font="default" size="100%">Babu, Sukumaran Santhosh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Diamondoid all-carbon porous aromatic framework host for lithium-sulfur batteries</style></title><secondary-title><style face="normal" font="default" size="100%">Small</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">3D polymers</style></keyword><keyword><style  face="normal" font="default" size="100%">Batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">Li-Sulfur battery</style></keyword><keyword><style  face="normal" font="default" size="100%">porous materials</style></keyword><keyword><style  face="normal" font="default" size="100%">pyrene</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">21</style></volume><pages><style face="normal" font="default" size="100%">2500388</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Lithium-sulfur batteries (LSBs) hold incredible potential as next-generation energy storage systems. However, practical applications of LSBs are significantly hindered by several critical challenges. For the first time, scalable all-carbon porous 3D polymers (3DPs) that do not contain heteroatoms or functional groups and do not require post-functionalization are investigated as hosts in lithium-sulfur batteries, demonstrating enhanced cycling stability and overall battery performance. The pyrene-containing 3DP exhibits 75% capacity retention after 600 cycles at 1 C and 52% capacity retention after 1300 cycles at 0.2 C, better than phenyl comprising 3DP. Furthermore, even at higher sulfur loading (4.1 mg cm(-2)) with an electrolyte/sulfur ratio of 5 mu L mg(-1), pyrene 3DP displayed a high capacity of 600 mA h g(-1) and stable performance over 250 cycles with negligible capacity fade. The defined pore structure of 3DPs prevents the migration of polysulfides through physical confinement and the large pi -clouds of 3DPs interact with the negative charge-bearing polysulfides generated in charge-discharge cycles through anion-pi interaction. In this way, The design ensures that the host 3DPs interact with neutral sulfur and anionic polysulfides, resulting in an excellent performance.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">23</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	12.1&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Senthilkumaran, Marimuthu</style></author><author><style face="normal" font="default" size="100%">Javaregowda, Bharathkumar H.</style></author><author><style face="normal" font="default" size="100%">Rajendran, Prakash Babu</style></author><author><style face="normal" font="default" size="100%">Balasubramanian, Rajalakshmi</style></author><author><style face="normal" font="default" size="100%">Ajithkumar, Thalasseril G.</style></author><author><style face="normal" font="default" size="100%">Ravindranathan, Sapna</style></author><author><style face="normal" font="default" size="100%">Krishnamoorthy, Kothandam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Mechanochemical large-scale rapid synthesis of ultrapure sodium hexafluorophosphate</style></title><secondary-title><style face="normal" font="default" size="100%">ChemPlusChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">ammonium hexafluorophosphate</style></keyword><keyword><style  face="normal" font="default" size="100%">Batteries</style></keyword><keyword><style  face="normal" font="default" size="100%">carbonates</style></keyword><keyword><style  face="normal" font="default" size="100%">sodium hexafluorophosphate</style></keyword><keyword><style  face="normal" font="default" size="100%">sodium vanadium phosphate</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">90</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Among the sodium battery electrolytes, sodium hexafluorophosphate (NaPF6) exhibits superior conductivity, anodic stability, and stable cathode electrolyte interface compared to other electrolytes. Therefore, the synthesis of pure NaPF6 through a simple process is very important. Usually, NaPF6 is synthesized using HF. In our approach, NaPF6 is synthesized by grinding dry ammonium hexafluorophosphate (NH4PF6) and sodium metal. Sodium injects an electron into the ammonium ion, which results in the formation of ammonia and hydrogen. The gram scale synthesis is completed in about 30 min. Purification of the product is not needed. The product purity is confirmed by various spectroscopic and electrochemical techniques. Usually, NaPF6 comprises NaF, HF, and solvents as impurities that affect the performance of SIBs. It has been confirmed that the NaPF6 synthesized by our mechanochemical approach in the absence of solvent is devoid of impurities despite the absence of product purification step. Furthermore, the synthesis of pure NaPF6 (250 g) is demonstrated using a grinder used as household item in cooking Indian pancakes, which costs about 300 USD. The duration of the synthesis of 250 g pure NaPF6 is 1 h. The purity of this sample is comparable to that of NaPF6 (5 g) synthesized using mortar and pestle.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	2.8&lt;/p&gt;
</style></custom4></record></records></xml>