<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hosamani, K. M.</style></author><author><style face="normal" font="default" size="100%">Hiremath, V. B.</style></author><author><style face="normal" font="default" size="100%">Keri, R. S.</style></author><author><style face="normal" font="default" size="100%">Harisha, R. S.</style></author><author><style face="normal" font="default" size="100%">Halligudi, Shivaraj B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synthesis of novel 2-alkyl substituted oleobenzimidazole derivatives using ethylene glycol as solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Canadian Journal of Chemistry-Revue Canadienne De Chimie</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">ethylene glycol</style></keyword><keyword><style  face="normal" font="default" size="100%">oleo-benzimidazole derivatives</style></keyword><keyword><style  face="normal" font="default" size="100%">oleochemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">unusual fatty acids</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2008</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">11</style></number><publisher><style face="normal" font="default" size="100%">NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS</style></publisher><pub-location><style face="normal" font="default" size="100%">BUILDING M 55, OTTAWA, ON K1A 0R6, CANADA</style></pub-location><volume><style face="normal" font="default" size="100%">86</style></volume><pages><style face="normal" font="default" size="100%">1030-1033</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The objective of this research was to conduct constructive organic chemistry by using ethylene glycol as an efficient solvent and to achieve yields that were comparable to or better than those in other media. The reaction parameters, such as temperature (150-200 degrees C), density, and reaction time (6 h), have been systematically studied to understand whether ethylene glycol is as an efficient solvent and can have a positive effect on the chemistry with good yields. By tuning the parameters, the yields have been optimized to around 70%-80%. Thus, a new class of 2-alkyl substituted oleo-benzimidazole derivatives have been synthesized and characterized by FTIR, (1)H NMR, (13)C NMR, MS, and elemental analysis.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">1.003</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kirali, Arun Arunima Balachandran</style></author><author><style face="normal" font="default" size="100%">Sreekantan, Sreejith</style></author><author><style face="normal" font="default" size="100%">Marimuthu, Banu</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Ce promoted Cu/?-Al2O3 catalysts for the enhanced selectivity of 1,2-pro-panediol from catalytic hydrogenolysis of glucose</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Communications</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">2-Propanediol&lt;/p&gt;</style></keyword><keyword><style  face="normal" font="default" size="100%">&lt;p&gt;1</style></keyword><keyword><style  face="normal" font="default" size="100%">Cu-Ce catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">ethylene glycol</style></keyword><keyword><style  face="normal" font="default" size="100%">Gamma alumina</style></keyword><keyword><style  face="normal" font="default" size="100%">Glucose hydrogenolysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">165</style></volume><pages><style face="normal" font="default" size="100%">106447</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Ce promoted Cu/gamma-Al2O3 catalysts were prepared with varying amounts of Cu (x = 0-10 wt%) and Ce (y = 0-15 wt%). The prepared catalysts were characterized and tested for the conversion of aqueous glucose (5 wt%) to 1,2propanediol in a batch reactor. 10%Ce-8%Cu/gamma-Al2O3 &amp;amp; nbsp;showed the complete conversion of glucose with 62.7% selectivity of 1,2-propanediol and total glycols (1,2-propanediol, ethylene glycol &amp;amp; 1,2-butanediol) of 81% at milder reaction conditions. Cu facilitated the hydrogenation activity and Ce loading optimize the acid/base sites of Cu/gamma-Al2O3 which obtain high selectivity of 1, 2-propanediol. Catalyst reusability is reported.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	3.510&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sreekantan, Sreejith</style></author><author><style face="normal" font="default" size="100%">Singh, Chandrodai Pratap</style></author><author><style face="normal" font="default" size="100%">Krishnamurty, Sailaja</style></author><author><style face="normal" font="default" size="100%">Marimuthu, Banu</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Investigation of the effect of zeolite supports and the role of W-species for one-pot catalytic conversion of cellulose to ethylene glycol: theoretical &amp; experimental studies.</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry-An Asian Journal</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Cellulose hydrogenolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">DFT studies</style></keyword><keyword><style  face="normal" font="default" size="100%">ethylene glycol</style></keyword><keyword><style  face="normal" font="default" size="100%">zeolites</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">18</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Endeavors were made to study the influence of various zeolite (HY, NaY, NaZSM-5 and HZSM-5) supports with (Al)-Ni-W metal combination catalysts for the ethylene glycol (EG) production, selectively from cellulose. From the experimental results ZSM-5 (NaZSM-5/73.3% &amp;amp; HZSM-5/67.7%) support is superior over HY &amp;amp; NaY support in selective EG production from cellulose. It was understood that W- species with oxygen vacancies (WO3-x, XPS analysis) plays an important role in producing the glycolaldehyde (GA) intermediate (via C-C cleavages), which on hydrogenation over Ni- sites selectively produce EG. Further, the studies based on the Density Functional Theory (DFT) were conducted to substantiate the involvement of the WO3-x species in the reaction. The adsorption energies and structural changes establish that the C-2-C-3 bond of the glucose elongates and thereby activates on adsorbing to WO3-x sites supporting the formation of GA. Activation of GA on Ni- sites is distinguished by an increase of 0.1 angstrom in C=O bond length, which facilitates the hydrogenation of C=O resulting in EG. The reaction pathway is explained through an analysis of CDD and DOS.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">4</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	4.839&lt;/p&gt;
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