<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Patil, V. S.</style></author><author><style face="normal" font="default" size="100%">Krishna, S. R.</style></author><author><style face="normal" font="default" size="100%">Hawaldar, Ranjit R.</style></author><author><style face="normal" font="default" size="100%">Gaikwad, A. B.</style></author><author><style face="normal" font="default" size="100%">Sathaye, S. D.</style></author><author><style face="normal" font="default" size="100%">Patil, K. R.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">One-step in situ synthesis of NHx-adsorbed rhodium nanocrystals at liquid-liquid interfaces for possible electrocatalytic applications</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Colloid and Interface Science</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Hydrazine hydrate</style></keyword><keyword><style  face="normal" font="default" size="100%">Liquid-liquid interface</style></keyword><keyword><style  face="normal" font="default" size="100%">Nanoparticles</style></keyword><keyword><style  face="normal" font="default" size="100%">Rhodium</style></keyword><keyword><style  face="normal" font="default" size="100%">Thin films</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2011</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><publisher><style face="normal" font="default" size="100%">ACADEMIC PRESS INC ELSEVIER SCIENCE</style></publisher><pub-location><style face="normal" font="default" size="100%">525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA</style></pub-location><volume><style face="normal" font="default" size="100%">358</style></volume><pages><style face="normal" font="default" size="100%">238-244</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Nearly monodisperse rhodium nanoparticles with adsorbed NHx were synthesized at the CCl4-water interface. The presence of NHx-adsorbed species was confirmed by energy-dispersive X-ray analysis (EDX) and X-ray photoelectron spectroscopy (XPS) studies. The synthesis of controlled size 2-38 nm rhodium particles was studied as a function of reducing agent concentration by transmission electron microscopy (TEM). HRTEM confirmed the formation of rhodium nanoparticles having fringe spacing consistent with reported Rh (1 1 1) planes. The continuity of these films over an area of 1 x 1 pm was revealed by atomic force microscopy (AFM) studies. The electrocatalytic application of these nanostructure Rh-NHx), thin films for formaldehyde oxidation in 0.5 M NaOH was investigated by cyclic voltammetry. The Rh nanoparticles formed by the present strategy are expected to be useful for other catalytic applications also. (C) 2011 Elsevier Inc. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><custom3><style face="normal" font="default" size="100%">Foreign
</style></custom3><custom4><style face="normal" font="default" size="100%">3.38
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gedam, Ashwin D.</style></author><author><style face="normal" font="default" size="100%">Katiya, Manish M.</style></author><author><style face="normal" font="default" size="100%">Dhonde, Madhukar G.</style></author><author><style face="normal" font="default" size="100%">Ganorkar, Kapil S.</style></author><author><style face="normal" font="default" size="100%">Thakare, Vijay J.</style></author><author><style face="normal" font="default" size="100%">Jadhao, Nitin L.</style></author><author><style face="normal" font="default" size="100%">Gajbhiye, Jayant M.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Aqueous-mediated selective reduction of Imidacloprid: a novel method for detoxification and detection</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Environmental Chemical Engineering</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">DFT analysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Extracted Imidacloprid</style></keyword><keyword><style  face="normal" font="default" size="100%">glucose</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrazine hydrate</style></keyword><keyword><style  face="normal" font="default" size="100%">Isoniazid</style></keyword><keyword><style  face="normal" font="default" size="100%">Sodium sulphite</style></keyword><keyword><style  face="normal" font="default" size="100%">Vaniline</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">122462</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	The extensive application of the neonicotinoid insecticide Imidacloprid has produced significant environmental concerns owing to its persistence and toxicity in aquatic ecosystems, thereby necessitating the development of straightforward and environmentally sustainable methods for its detection and detoxification. In the present study, we demonstrate for the first time that selective reducing agents can function as environmentally friendly chromogenic reagents for the detoxification and detection of Imidacloprid in contaminated water. The insecticide was treated with various reducing agents, such as aqueous solution of glucose, sodium sulphite, hydrazine hydrate, isoniazid, and vanillin, leading to the reduction of Imidacloprid and the formation of a white solid product. The reaction process provides a straightforward visual indication, suggesting the possible use of these reagents as eco-friendly chromogenic systems for pesticide monitoring. The chemical identification and structural properties of the resultant product were elucidated and confirmed by standard spectroscopy techniques. Moreover, the reaction pathway was systematically examined through experimental observations and theoretical studies. Density Functional Theory (DFT) calculations were conducted with the Gaussian program to provide a more profound understanding of the reaction pathway. The integrated experimental and computational findings offer a reliable mechanistic insight into the reduction process and highlight the potential of selective reducing agents as environmentally friendly reagents for the detection and detoxification of Imidacloprid in aquatic ecosystems.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	7.5&lt;/p&gt;
</style></custom4></record></records></xml>