<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pachfule, Pradip</style></author><author><style face="normal" font="default" size="100%">Chen, Yifei</style></author><author><style face="normal" font="default" size="100%">Sahoo, Subash Chandra</style></author><author><style face="normal" font="default" size="100%">Jiang, Jianwen</style></author><author><style face="normal" font="default" size="100%">Banerjee, Rahul</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Structural isomerism and effect of fluorination on gas adsorption in copper-tetrazolate based metal organic frameworks</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry of Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">CO2 adsorption</style></keyword><keyword><style  face="normal" font="default" size="100%">fluorination</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogen storage</style></keyword><keyword><style  face="normal" font="default" size="100%">Metal-organic framework</style></keyword><keyword><style  face="normal" font="default" size="100%">structural isomerism</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2011</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">11</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">23</style></volume><pages><style face="normal" font="default" size="100%">2908-2916</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Synthesis, structure, and gas adsorption properties of three Metal Organic Frameworks (MOFs) synthesized from predesigned ligands 4-(1H-tetrazole-5-yl)benzoic acid (4-TBA) and 2-fluoro-4-(1H-tetrazole-5-yl)benzoic acid (2F-4-TBA) along with Cu(II) as an metal precursor has been reported. Among these MOFs, Cu-9(4-TBA)(10)(C2H5OH)(2) (Cu-TBA-1) and Cu-2(4-TBA)(2)(DMF)(C2H5OH) (Cu-TBA-2) are structural isomers. Whereas, Cu-2(4-TBA)(2)(DMF)(C2H5OH) (Cu-TBA-2) and Cu-2(2-F-4-TBA)(2)(DMF)(2) (Cu-TBA-2F) have similar crystal structure. N-2 adsorption isotherms of the activated sample of Cu-TBA-1 and -2 exhibit types-I sorption behavior with a Langmuir and Brunauer-Emmett-Teller (BET) surface area of 686, 402 m(2)/g and 616, 356 m(2)/g, respectively. It is noteworthy that Cu-TBA-1 and -2 adsorbs 1.16 and, 1.54 wt % H-2, while Cu-TBA-2F adsorbs 0.67 wt % at 77 K and 1 atm. On the other hand, Cu-TBA-1 and -2 adsorb 3.08 and 2.54 mmol/g, while Cu-TBA-2F adsorbs 1.27 mmol/g of CO2 at 298 K and 1 bar pressure. H-2 adsorption sites in Cu-TBA-2 and -2F have been analyzed by molecular simulation.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">11</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">7.286
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Banerjee, Rahul</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Functionalized metal organic frameworks (MOFs) for reversible gas storage and sequestration applications</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of the Indian Chemical Society</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">carbon capture</style></keyword><keyword><style  face="normal" font="default" size="100%">CO2 adsorption</style></keyword><keyword><style  face="normal" font="default" size="100%">fluorination</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogen storage</style></keyword><keyword><style  face="normal" font="default" size="100%">Metal-organic framework</style></keyword><keyword><style  face="normal" font="default" size="100%">structural isomerism</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">9</style></number><publisher><style face="normal" font="default" size="100%">SCIENTIFIC PUBL-INDIA</style></publisher><pub-location><style face="normal" font="default" size="100%">5-A, NEW PALI RD, PO BOX 91, NEAR HOTEL TAJ HARI MAHAL, JODHPUR, 342 003, INDIA</style></pub-location><volume><style face="normal" font="default" size="100%">89</style></volume><pages><style face="normal" font="default" size="100%">1197-1202</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The decreasing amount of fossil fuels and increasing threat of global warming from the pollutants have driven the search for clean energy source. Energy sources from fossil fuels still remain in the forefront despite being a major source of increased CO2 content in the atmosphere. Metal Organic Frameworks (MOFs) have emerged as promising materials for hydrogen storage and CO2 sequestration. Several factors influencing the hydrogen uptake of porous MOFs such as surface area, catenation, ligand functionalization, doping with alkali metals and unsaturated metal centers have been extensively studied. Similarly, well defined periodicity and tunable pore sizes along with less basic amino-functionalized MOFs enables them favorable for fast and reversible CO2 gas adsorption at low partial pressure and room temperature. In this review we present diverse aspects of metal organic frameworks like fluorination, amino functionalization for high hydrogen storage and CO2 sequestration capabilities.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">9</style></issue><custom3><style face="normal" font="default" size="100%">Indian</style></custom3><custom4><style face="normal" font="default" size="100%">0.251
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Said, Madhukar S.</style></author><author><style face="normal" font="default" size="100%">Pandole, Satish</style></author><author><style face="normal" font="default" size="100%">Suryavanshi, Amol</style></author><author><style face="normal" font="default" size="100%">Kumar, Pradeep</style></author><author><style face="normal" font="default" size="100%">Gajbhiye, Jayan M.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Acidic handle assemble heterogeneous carbocatalyst for facile aliphatic nucleophilic fluorination</style></title><secondary-title><style face="normal" font="default" size="100%">ChemistrySelect</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">fluorination</style></keyword><keyword><style  face="normal" font="default" size="100%">heterogeneous catalysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">4</style></volume><pages><style face="normal" font="default" size="100%">10960-10964</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Acidic handle (-SO3H) assemble carbonaceous catalyst synthesized from glucose acts as a modulator for the nucleophilic fluorination reaction. The heterogeneous catalyst works with various alkyl sulfonate, halide and metal fluoride (MF), to offer a high yield of fluorinated products up to 93%. This carbonaceous catalyst is recyclable for more than five times, with no major loss of activity.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">36</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;1.716&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Said, Madhukar S.</style></author><author><style face="normal" font="default" size="100%">Mishra, Ankita</style></author><author><style face="normal" font="default" size="100%">Pandole, Satish</style></author><author><style face="normal" font="default" size="100%">Nayak, Rashmi A.</style></author><author><style face="normal" font="default" size="100%">Kumar, Pradeep</style></author><author><style face="normal" font="default" size="100%">Gajbhiye, Jayant M.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Regioselective one-pot synthesis of 3-fluoro-imidazo[1,2-a]pyridines from styrene</style></title><secondary-title><style face="normal" font="default" size="100%">Asian Journal of Organic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">fluorination</style></keyword><keyword><style  face="normal" font="default" size="100%">imidazopyridines (F-IMPY)</style></keyword><keyword><style  face="normal" font="default" size="100%">One-pot synthesis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT</style></date></pub-dates></dates><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;A one-pot synthesis of C-3 fluorinated imidazopyridines (F-IMPY) is reported under the additive-free conditions from commercially available styrene and 1-fluoropyridinium tetrafluoroborate as a fluorine source. The substrate styrene undergoes keto-bromination/condensation/fluorination transformation in three sequential steps to furnish F-IMPY. This one-pot synthesis method exhibits broad substrate scope and good functional group tolerance with a good yield (up to 82%).&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article; Early Access</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;2.496&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Said, Madhukar S.</style></author><author><style face="normal" font="default" size="100%">Khonde, Nilesh S.</style></author><author><style face="normal" font="default" size="100%">Thorat, Meghana N.</style></author><author><style face="normal" font="default" size="100%">Atapalkar, Ranjit S.</style></author><author><style face="normal" font="default" size="100%">Kulkarni, Amol A.</style></author><author><style face="normal" font="default" size="100%">Gajbhiye, Jayant</style></author><author><style face="normal" font="default" size="100%">Dastager, Syed G.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">New TBAF complex, highly stable, facile and selective source for nucleophilic fluorination: applications in batch and flow chemistry</style></title><secondary-title><style face="normal" font="default" size="100%">Asian Journal of Organic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Flow synthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">fluorination</style></keyword><keyword><style  face="normal" font="default" size="100%">green chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">Sustainable Chemistry</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">9</style></volume><pages><style face="normal" font="default" size="100%">1022-1026</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Natural polysaccharides supported tetrabutylammonium fluoride (TBAF) complexes are prepared and found to be highly stable and selective fluoride source for well-renowned nucleophilic (SN2 type) fluorination reactions for the first time. Bacterial cellulose, plant cellulose, pectin, and starch derived TBAF complexes are synthesized, characterized (using SEM, TEM, and NMR techniques) and studied for their stability and reactivity. Heterogeneous bacterial cellulose-TBAF complex (NBu4(Bac-cell-OH)F) 1 was found to be highly stable and non-hygroscopic among all complexes, which gave high yields of fluorinated products in multi-gram scale in shorter reaction time. The primarily developed batch protocol was extended to solid-solid continuous flow reaction using an in-house built screw reactor, which furnished products in a few seconds of residence time (tR=20-25 sec) and excellent yields.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;3.130&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kewat, Heera Lal</style></author><author><style face="normal" font="default" size="100%">Dutta, Debangkana</style></author><author><style face="normal" font="default" size="100%">Ajithkumar, T. G.</style></author><author><style face="normal" font="default" size="100%">Chavda, Dhruvil</style></author><author><style face="normal" font="default" size="100%">Sharma, Rahul Kumar</style></author><author><style face="normal" font="default" size="100%">Tiwari, Mrityunjay K.</style></author><author><style face="normal" font="default" size="100%">Sidiqi, Ubaid</style></author><author><style face="normal" font="default" size="100%">Manna, Moutusi</style></author><author><style face="normal" font="default" size="100%">Nigam, Sandeep</style></author><author><style face="normal" font="default" size="100%">Ghosh, Pushpal</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Ionic liquid driven Refined functionalization of graphene oxide: An insight via combined experiments and theory</style></title><secondary-title><style face="normal" font="default" size="100%">Carbon</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">fluorination</style></keyword><keyword><style  face="normal" font="default" size="100%">Functionalization</style></keyword><keyword><style  face="normal" font="default" size="100%">graphene oxide</style></keyword><keyword><style  face="normal" font="default" size="100%">ionic liquids</style></keyword><keyword><style  face="normal" font="default" size="100%">Luminescence</style></keyword><keyword><style  face="normal" font="default" size="100%">Photocatalysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">243</style></volume><pages><style face="normal" font="default" size="100%">120571</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Functionalizing graphene and its derivative, or doping them with heteroatoms can significantly enhance their optoelectronic, photonic and bio-photonic properties; but controlled and tuneable functionalization of GO is still in their infancy. Herein, a series of functionalized graphene oxide (FGO) are synthesized solvothermally by using task specific ionic liquids (ILs) of varying alkyl chain length; 1-alkyl-3-methylimidazolium tetra fluoroborate, [Cnmim]BF4 (n = 2, 4 etc.). ILs are not only used as a solvent but also as source of fluoride ion for functionalization of GO. A drastic decrease in the oxygen containing functional groups of GO upon fluorination is evidenced by FTIR, Raman, XPS, EDX analysis and electrochemical study. Solid state 19F NMR spectroscopy indicates that, fluorination happens exclusively in edge positions, not on basal planes. Band gap of FGOs decreases along with increasing the chain length of ILs. Further, intense blue emission and high photocatalytic efficiency, using crystal violet as model dye are observed for all the FGOs under visible light. The tailored functionalization by varying alkyl chain length of IL has been rationalized by DFT calculations. It has been realized that owing to the ease of dissociation for [Cnmim]BF4 complexes with n &amp;gt;= 10; greater extent of fluorination/functionalization of GO has been observed. Elimination of a non-covalent interaction on increasing the alkyl chain length has been attributed for lower stability of higher chain length IL which in turn renders ease of dissociation. Easy yet controlled functionalization of GO using tuneable ILs can open a new direction in the environment friendly synthesis and applications.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;11.6&lt;/p&gt;
</style></custom4></record></records></xml>