<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Chikkali, Samir H.</style></author><author><style face="normal" font="default" size="100%">van der Vlugt, Jarl Ivar</style></author><author><style face="normal" font="default" size="100%">Reek, Joost N. H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation</style></title><secondary-title><style face="normal" font="default" size="100%">Coordination Chemistry Reviews</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Asymmetric hydroformylation</style></keyword><keyword><style  face="normal" font="default" size="100%">Catalyst resting state</style></keyword><keyword><style  face="normal" font="default" size="100%">Hybrid ligand design</style></keyword><keyword><style  face="normal" font="default" size="100%">In situ spectroscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">Rhodium</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE SA</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 564, 1001 LAUSANNE, SWITZERLAND</style></pub-location><volume><style face="normal" font="default" size="100%">262</style></volume><pages><style face="normal" font="default" size="100%">1-15</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;This review aims to illustrate recent advances in the application of hybrid diphosphorus ligands for the Rh catalysed hydroformylation of alkenes, discussing the most prevalent classes of hybrid systems, i.e. phosphine-phosphinite, phosphine-phosphonite, phosphine-phosphite, phosphite-phosphoramidite and phosphite-phosphoramidite and comparing their performance with relevant C-2 symmetric counterparts. In order to introduce the field and put the results in context, a short overview on Rh hydroformylation is provided. Available spectroscopic (in situ) data on the coordination modes of hybrid phosphorus ligands and the catalytic performance of these systems in asymmetric hydroformylation of vinyl arenes are reported. Potential avenues for future research are shortly discussed. (C) 2013 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">12.239</style></custom4></record></records></xml>