<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ahire, Milind M.</style></author><author><style face="normal" font="default" size="100%">Mhaske, Santosh B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Direct allylation of in situ generated aldehyde acyl anions by synergistic NHC and palladium catalysis</style></title><secondary-title><style face="normal" font="default" size="100%">Angewandte Chemie-International Edition</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">aldehyde umpolung</style></keyword><keyword><style  face="normal" font="default" size="100%">C allylation</style></keyword><keyword><style  face="normal" font="default" size="100%">N-heterocyclic carbenes</style></keyword><keyword><style  face="normal" font="default" size="100%">Palladium</style></keyword><keyword><style  face="normal" font="default" size="100%">synergistic catalysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2014</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">27</style></number><publisher><style face="normal" font="default" size="100%">WILEY-V C H VERLAG GMBH</style></publisher><pub-location><style face="normal" font="default" size="100%">BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY</style></pub-location><volume><style face="normal" font="default" size="100%">53</style></volume><pages><style face="normal" font="default" size="100%">7038-7042</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The direct regioselective allylation of in situ generated aldehyde acyl anions has been achieved by synergistic NHC and Pd catalysis. It provides an efficient access to valuable beta,gamma-unsaturated ketones under mild reaction conditions starting from easily accessible allylic carbonates and aldehydes without any preactivation. The synergistic catalysis method demonstrated herein adds a new dimension to the area of metal-mediated C allylation.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">27</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;11.709&lt;/p&gt;</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Das, Tamal Kanti</style></author><author><style face="normal" font="default" size="100%">Biju, Akkattu T.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">N-heterocyclic carbene (NHC)-catalyzed transformations for the synthesis of heterocycles</style></title><secondary-title><style face="normal" font="default" size="100%">Progress in Heterocyclic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">aldehyde umpolung</style></keyword><keyword><style  face="normal" font="default" size="100%">Aldimine umpolung</style></keyword><keyword><style  face="normal" font="default" size="100%">benzoin reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">Breslow intermediates</style></keyword><keyword><style  face="normal" font="default" size="100%">Enantioselective synthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">Heterocyclic synthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">N-Heterocyclic carbene</style></keyword><keyword><style  face="normal" font="default" size="100%">Stetter reaction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">31</style></volume><pages><style face="normal" font="default" size="100%">1-82</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;N-heterocyclic carbene (NHC)-based organocatalysis has been widely used for unconventional access to various target molecules. The use of chiral NHCs in the process results in the enantioselective synthesis of various heterocycles. The underlying principle of many of the NHC-catalyzed reactions is the remarkable ability of NHCs to reverse the normal mode of reactivity of aldehydes (umpolung). NHCs can catalyze transformations proceeding via the umpolung or nonumpolung mode for the synthesis of various functionalized molecules. The recent advances in the application of NHCs for the synthesis of various heterocyclic compounds are highlighted in this chapter.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Book Chapter</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
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