<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Dharmapurikar, Satej S.</style></author><author><style face="normal" font="default" size="100%">Arulkashmir, Arulraj</style></author><author><style face="normal" font="default" size="100%">Das, Chayanika</style></author><author><style face="normal" font="default" size="100%">Muddellu, Pooja</style></author><author><style face="normal" font="default" size="100%">Krishnamoorthy, Kothandam</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Enhanced hole carrier transport due to increased intermolecular contacts in small molecule based field effect transistors</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">hole mobility</style></keyword><keyword><style  face="normal" font="default" size="100%">i-indigo</style></keyword><keyword><style  face="normal" font="default" size="100%">organic field effect transistor</style></keyword><keyword><style  face="normal" font="default" size="100%">quadrupole interaction</style></keyword><keyword><style  face="normal" font="default" size="100%">small molecules</style></keyword><keyword><style  face="normal" font="default" size="100%">triphenylamine</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">15</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">5</style></volume><pages><style face="normal" font="default" size="100%">7086-7093</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Small molecules and oligomers can be synthesized with very high purity and precise molecular weights, but they often do not form uniform thin films while processed from solution. Decreased intermolecular contacts between the small molecules are another disadvantage. To increase the intermolecular contacts in small molecules, we have chosen i-indigo, as one of the conjugated molecular units. The electron poor i-indigo has been connected with electron rich triphenylamine to synthesize a donor-acceptor-donor type small molecule. The propeller shaped triphenylamine helps to increase the solubility of the small molecule as well as isotropic charge transport. The intermolecular spacing between the molecules has been found to be low and did not vary as a function of thermal annealing. This implies that the intermolecular contacts between the small molecules are enhanced, and they do not vary as a function of thermal annealing. Organic field effect transistors (OFET) fabricated using a small molecule exhibited a hole carrier mobility (mu) of 0.3 cm(2)/(V s) before thermal annealing. A marginal increase in mu was observed upon thermal annealing at 150 degrees C, which has been attributed to changes in thin film morphology. The morphology of the thin films plays an important role in charge transport in addition to the intermolecular spacing that can be modulated with a judicious choice of the conjugated molecular unit.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">15</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">5.9
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Yadav, Sandeep</style></author><author><style face="normal" font="default" size="100%">Saha, Sumana</style></author><author><style face="normal" font="default" size="100%">Sen, Sakya S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Compounds with low-valent p-block elements for small molecule activation and catalysis</style></title><secondary-title><style face="normal" font="default" size="100%">Chemcatchem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">activation</style></keyword><keyword><style  face="normal" font="default" size="100%">carbenes</style></keyword><keyword><style  face="normal" font="default" size="100%">main-group elements</style></keyword><keyword><style  face="normal" font="default" size="100%">silylenes</style></keyword><keyword><style  face="normal" font="default" size="100%">small molecules</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2016</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">3</style></number><publisher><style face="normal" font="default" size="100%">WILEY-V C H VERLAG GMBH</style></publisher><pub-location><style face="normal" font="default" size="100%">POSTFACH 101161, 69451 WEINHEIM, GERMANY</style></pub-location><volume><style face="normal" font="default" size="100%">8</style></volume><pages><style face="normal" font="default" size="100%">486-501</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The past decade has witnessed staggering progress in the chemistry of compounds with low-valent main-group elements. Although these discoveries are mostly fundamental by nature, these compounds show promising reactivity towards small molecule activation. The reactivity of these compounds stems from the modest HOMO-LUMO energy gap; a characteristic known for the transition metals. The journey began in 2005 with the facile activation of dihydrogen by an alkyne analog of germanium [ArGeGeAr; Ar=2,6-Trip(2)-C6H3 (Trip=2,4,6-iPr(3)-C6H2)]. Subsequently, tremendous progress has been achieved in understanding and elucidating the potential of these compounds to activate small molecules as well as to use them in a variety of stoichiometric and catalytic transformations. In this review, we focus on developments in the activation of H-2, NH3, CO, and CO2 by compounds with multiply bound or open shell main-group elements. Emphasis will be given to their catalytic activity.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">4.724</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Nareshkumar, Ambekar</style></author><author><style face="normal" font="default" size="100%">Subbarao, Sindhu</style></author><author><style face="normal" font="default" size="100%">Vennapusa, Amarnatha Reddy</style></author><author><style face="normal" font="default" size="100%">Ashwin, Vargheese</style></author><author><style face="normal" font="default" size="100%">Banarjee, Reema</style></author><author><style face="normal" font="default" size="100%">Kulkarni, Mahesh J.</style></author><author><style face="normal" font="default" size="100%">Ramu, Vemanna S.</style></author><author><style face="normal" font="default" size="100%">Udayakumar, Makarla</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Enzymatic and non-enzymatic detoxification of reactive carbonyl compounds improves the oxidative stress tolerance in cucumber, tobacco and rice seedlings</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Plant Growth Regulation</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Oxidative stress</style></keyword><keyword><style  face="normal" font="default" size="100%">plant growth</style></keyword><keyword><style  face="normal" font="default" size="100%">Reactive carbonyl scavengers</style></keyword><keyword><style  face="normal" font="default" size="100%">Seed germination</style></keyword><keyword><style  face="normal" font="default" size="100%">small molecules</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">39</style></volume><pages><style face="normal" font="default" size="100%">1359-1372</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Detoxification of reactive carbonyl compounds (RCC) is crucial to sustain cellular activity to improve plant growth and development. Seedling growth is highly affected by accumulation of RCC under stress. We report non-enzymatic, enzymatic mechanisms of detoxification of RCC in the cucumber, tobacco and rice seedling systems exposed to glucose, NaCl, methyl viologen (MV) induced oxidative stress. The cucumber seedlings exposed to carbonyl stress had higher levels of malondialdehyde (MDA), protein carbonyls (PCs) and advanced glycation end-product N-carboxymethyl-lysine (AGE-CML) that negatively affected the seedling growth. The overexpression of enzyme encoding aldo-keto reductase-1 (AKR1) in tobacco and rice showed detoxification of RCC, MDA and methylglyoxal (MG) with improved seedling growth under glucose, NaCl and MV-induced oxidative stress. Further, small molecules like acetylsalicylic acid (ASA), aminoguanidine (AG), carnosine (Car), curcumin (Cur) and pyridoxamine (PM) showed detoxification of RCC non-enzymatically and rescued the cucumber seedling growth from glucose, NaCl and MV-stress. In autotrophically grown rice seedlings these molecules substantially improved seedling growth under MV-induced oxidative stress. Seedlings treated with the small molecules sustained higher guaiacol peroxidase (GPX) enzyme activity signifying the role of small molecules in reducing carbonyl stress-induced protein inactivation and AGE-CML protein modifications. The results showed that besides enzymatic detoxification of RCC, the small molecules also could reduce cytotoxic effect of RCC under stress. The study demonstrates that small molecules are attractive compounds to improve the seedling growth under stress conditions.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;2.672&lt;/p&gt;
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