<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Tothadi, Srinu</style></author><author><style face="normal" font="default" size="100%">Koner, Kalipada</style></author><author><style face="normal" font="default" size="100%">Dey, Kaushik</style></author><author><style face="normal" font="default" size="100%">Addicoat, Matthew</style></author><author><style face="normal" font="default" size="100%">Banerjee, Rahul</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Morphological evolution of two-dimensional porous hexagonal trimesic acid framework</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">dye adsorption</style></keyword><keyword><style  face="normal" font="default" size="100%">hollow hexagonal rod</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrogen-bonded organic framework</style></keyword><keyword><style  face="normal" font="default" size="100%">morphology evaluation</style></keyword><keyword><style  face="normal" font="default" size="100%">trimesic acid</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">12</style></volume><pages><style face="normal" font="default" size="100%">15588-15594</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hexagonal single crystal structure (Form II) of trimesic acid (TMA) has been isolated by dissolving the interpenetrated Form I of TMA in tetrahydrofuran. Form II (hexagonal) was converted to Form I (interpenetrated) at room temperature through some intermediate structures. A detailed time-dependent FESEM study shows that the external morphology of Form II (hexagonal) is a hollow hexagonal tube that mimics its crystal structure. The block-shaped (morphology) of Form I (interpenetrated) was converted to the hollow hexagonal tube through some intermediate morphologies which are corresponding to particular crystal structures. Here, we have established a strong correlation between crystal structures with the morphology. These hollow tubes have been employed for Rhodamine B dye adsorption studies and showed an uptake of 82%, much more significant than Form I (interpenetrated) (39%) due to the presence of a pore channel in the crystal structure.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">13</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;8.758&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mohammed, Abdul Khayum</style></author><author><style face="normal" font="default" size="100%">Raya, Jesus</style></author><author><style face="normal" font="default" size="100%">Pandikassala, Ajmal</style></author><author><style face="normal" font="default" size="100%">Addicoat, Matthew A.</style></author><author><style face="normal" font="default" size="100%">Gaber, Safa</style></author><author><style face="normal" font="default" size="100%">Aslam, Mohamed</style></author><author><style face="normal" font="default" size="100%">Ali, Liaqat</style></author><author><style face="normal" font="default" size="100%">Kurungot, Sreekumar</style></author><author><style face="normal" font="default" size="100%">Shetty, Dinesh</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Chemically gradient hydrogen-bonded organic framework crystal film</style></title><secondary-title><style face="normal" font="default" size="100%">Angewandte Chemie-International Edition</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Chemical Gradience</style></keyword><keyword><style  face="normal" font="default" size="100%">Crystal Films</style></keyword><keyword><style  face="normal" font="default" size="100%">Free-Standing Films</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrogen-bonded organic framework</style></keyword><keyword><style  face="normal" font="default" size="100%">Interfacial Chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">proton conductivity</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">62</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Hydrogen-bonded organic frameworks (HOFs) are ordered supramolecular solid structures, however, nothing much explored as centimetre-scale self-standing films. The fabrication of such crystals comprising self-supported films is challenging due to the limited flexibility and interaction of the crystals, and therefore studies on two-dimensional macrostructures of HOFs are limited to external supports. Herein, we introduce a novel chemical gradient strategy to fabricate a crystal-deposited HOF film on an in situ-formed covalent organic polymer film (Tam-Bdca-CGHOF). The fabricated film showed versatility in chemical bonding along its thickness from covalent to hydrogen-bonded network. The kinetic-controlled Tam-Bdca-CGHOF showed enhanced proton conductivity (8.3x10(-5) S cm(-1)) compared to its rapid kinetic analogue, Tam-Bdca-COP (2.1x10(-5) S cm(-1)), which signifies the advantage of bonding-engineering in the same system.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">29</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	16.6&lt;/p&gt;
</style></custom4></record></records></xml>