<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Nagare, Amit S.</style></author><author><style face="normal" font="default" size="100%">Kumar, Anil</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Eutectic mixture-directed kinetics of Diels-Alder reaction</style></title><secondary-title><style face="normal" font="default" size="100%">Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical &amp; Analytical Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">carbohydrates</style></keyword><keyword><style  face="normal" font="default" size="100%">Cycloaddition</style></keyword><keyword><style  face="normal" font="default" size="100%">Diels-Alder reaction</style></keyword><keyword><style  face="normal" font="default" size="100%">Dimethylurea</style></keyword><keyword><style  face="normal" font="default" size="100%">kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">Reaction rates</style></keyword><keyword><style  face="normal" font="default" size="100%">solvent effects</style></keyword><keyword><style  face="normal" font="default" size="100%">Urea</style></keyword><keyword><style  face="normal" font="default" size="100%">viscosity</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2011</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">6</style></number><publisher><style face="normal" font="default" size="100%">NATL INST SCIENCE COMMUNICATION-NISCAIR</style></publisher><pub-location><style face="normal" font="default" size="100%">DR K S KRISHNAN MARG, PUSA CAMPUS, NEW DELHI 110 012, INDIA</style></pub-location><volume><style face="normal" font="default" size="100%">50</style></volume><pages><style face="normal" font="default" size="100%">788-792</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;In the search for environmentally benign solvent media, a new class of solvents composed of mixtures of carbohydrates with urea or methylated urea has been noted to be effective in enhancing the reaction rates of a bimolecular organic reaction like the Diels-Alder reaction of cyclopentadiene with methyl acrylate. The viscosity of these media appears to be an important parameter in controlling the second order kinetics.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">6</style></issue><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Indian&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">0.76</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Rai, Gitanjali</style></author><author><style face="normal" font="default" size="100%">Kumar, Anil</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Probing thermal interactions of ionic liquids with dimethyl sulfoxide</style></title><secondary-title><style face="normal" font="default" size="100%">Chemphyschem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">calorimetry</style></keyword><keyword><style  face="normal" font="default" size="100%">dimethyl sulfoxide</style></keyword><keyword><style  face="normal" font="default" size="100%">ionic liquids</style></keyword><keyword><style  face="normal" font="default" size="100%">solvent effects</style></keyword><keyword><style  face="normal" font="default" size="100%">thermochemistry</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">7, SI</style></number><publisher><style face="normal" font="default" size="100%">WILEY-V C H VERLAG GMBH</style></publisher><pub-location><style face="normal" font="default" size="100%">BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY</style></pub-location><volume><style face="normal" font="default" size="100%">13</style></volume><pages><style face="normal" font="default" size="100%">1927-1933</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Interactions between ionic liquids and dimethyl sulfoxide (DMSO) are probed by isothermal titration calorimetry. The excess partial molar enthalpies of ionic liquids H-IL(E) in DMSO are discussed in terms of solutesolvent interactions. The specific interaction theory originally developed by Pitzer is used to analyze the apparent molar enthalpy phi(L) of ionic liquids in DMSO with the help of ion-interaction parameters. Furthermore, quantitative information on solvent reorganization and clathrate formation is obtained and interpreted.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">3.349
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Beniwal, Vijay</style></author><author><style face="normal" font="default" size="100%">Kumar, Anil</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synergistic effects and correlating polarity parameters in binary mixtures of ionic liquids</style></title><secondary-title><style face="normal" font="default" size="100%">Chemphyschem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">green chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">ionic liquids</style></keyword><keyword><style  face="normal" font="default" size="100%">liquids</style></keyword><keyword><style  face="normal" font="default" size="100%">noncovalent interactions</style></keyword><keyword><style  face="normal" font="default" size="100%">solvent effects</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2015</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">5</style></number><publisher><style face="normal" font="default" size="100%">WILEY-V C H VERLAG GMBH</style></publisher><pub-location><style face="normal" font="default" size="100%">BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY</style></pub-location><volume><style face="normal" font="default" size="100%">16</style></volume><pages><style face="normal" font="default" size="100%">1026-1034</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Understanding how a chemical reaction proceeds in solution requires precise knowledge of solute-solvent interactions. Certain issues involved in ionic liquid binary mixtures are still not clearly understood, including: 1) the effects of hydrogen-bond-acceptor basicity () of solvents on the synergistic effects found in ionic liquid-alcohol mixtures, 2) the interrelation between the polarity parameters in binary mixtures, and 3) the application of a model for the description of normalised electronic transition energy for all the binary mixtures. Here, a detailed analysis of polarity parameters in both hydrophilic and hydrophobic ionic liquids has been carried out. A three-parameter model developed by Roses et al. [J. Chem. Soc. Perkin Trans. 2 1997, 13411348] was found to be applicable to all the binary mixtures, and synergistic effects are generated as a result of high values of alcohols compared with those of the ionic liquids. A strong correlation was observed in the values and hydrophobicities of pure ionic liquids, suggesting that values can play a role in describing synergism.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">3.138</style></custom4></record></records></xml>