<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bhowmik, Susmita</style></author><author><style face="normal" font="default" size="100%">Darbha, Srinivas</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Advances in solid catalysts for selective hydrogenolysis of glycerol to 1,3-propanediol</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Reviews-Science and Engineering</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">1</style></keyword><keyword><style  face="normal" font="default" size="100%">3-Propanediol</style></keyword><keyword><style  face="normal" font="default" size="100%">bifunctional metal-metal oxide catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">Glycerol</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogenolysis</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Glycerol is one of the top 12 platform chemicals obtained from biomass. Its surplus availability as a by-product of biodiesel, fat-splitting and soap manufacturing industries and affordable price lends significant opportunity for its valorization, using solid catalysts, into propanediols (PDOs), particularly to 1,3-propanediol (1,3-PDO), by selective hydrogenolysis. 1,3-PDO is an important chemical with wide applications including that as a precursor in polymers manufacturing. However, the synthesis of 1,3-PDO by selective cleavage of the secondary C-O bond of glycerol in the presence of hydrogen (instead of the primary C-O bond yielding 1,2-PDO) is highly challenging. Of late, supported Pt and Ir catalysts in combination with a reducible oxide (WO(x)or ReOx) were found selective for 1,3-PDO formation. Support, metals composition and additives (co-added metals) affect the performance of these catalysts. Detailed investigations revealed that metal dispersion, electronic connectivity between metal and metal oxide/support, hydrogen activation/spillover and Bronsted acidity are some parameters that influence the activity and selectivity of these bi-functional, metal-metal oxide catalysts. This review summarizes the latest advances in these solid catalysts for selective hydrogenolysis of glycerol to 1,3-PDO, a monomer for advanced polymers.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Review</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign (Early Access: Aug 2020)&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;11.389&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Dasgupta, Diptarka</style></author><author><style face="normal" font="default" size="100%">Sidana, Arushdeep</style></author><author><style face="normal" font="default" size="100%">Ghosh, Prasenjit</style></author><author><style face="normal" font="default" size="100%">Sharma, Tripti</style></author><author><style face="normal" font="default" size="100%">Singh, Jasvinder</style></author><author><style face="normal" font="default" size="100%">Prabhune, Asmita</style></author><author><style face="normal" font="default" size="100%">More, Snehal</style></author><author><style face="normal" font="default" size="100%">Bhaskar, Thallada</style></author><author><style face="normal" font="default" size="100%">Ghosh, Debashish</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Energy and life cycle impact assessment for xylitol production from corncob</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Cleaner Production</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">Life cycle impact assessment</style></keyword><keyword><style  face="normal" font="default" size="100%">simulation</style></keyword><keyword><style  face="normal" font="default" size="100%">xylitol</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">278</style></volume><pages><style face="normal" font="default" size="100%">123217</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The conversion of biobased feedstocks into energy and value-added chemicals is one main approach to address the current global challenge for waste mitigation through the biorefinery mode. Corncob biomass which is one of the most abundant agricultural residue in India with a high hemicellulose content, can serve as a potential low-cost raw material for food-grade xylitol production. The present study demonstrates a process for xylitol production from corncob biomass with detailed energy and life cycle analysis for viability assessment. The major highlight of the process is the use of microbial fermentation, where biomass-derived D-xylose is converted to xylitol with high selectivity. Overall, 0.502 kg of xylitol crystals could be produced from 3.5 kg of corncob biomass. Simulation analysis revealed that the evaporators are the primary consumers of energy, and the process of heat integration can significantly reduce the energy requirements of the overall process. Environmental impacts of the system evaluated showed emission results of 8.68 kg CO2 equivalent and revealed that marine aquatic and freshwater eco-toxicity are the only possible contributors to the environment. The results suggest that the process would have favourable energy balances, which can be used in pilot plant and heat exchanger network design and operation for xylitol production scale up to 500 L. (C) 2020 Elsevier Ltd. All rights reserved.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">9.297
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sudarsanam, Putla</style></author><author><style face="normal" font="default" size="100%">Gupta, Navneet Kumar</style></author><author><style face="normal" font="default" size="100%">Mallesham, Baithy</style></author><author><style face="normal" font="default" size="100%">Singh, Nittan</style></author><author><style face="normal" font="default" size="100%">Kalbande, Pavan Narayan</style></author><author><style face="normal" font="default" size="100%">Reddy, Benjaram M.</style></author><author><style face="normal" font="default" size="100%">Sels, Bert F.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Supported MoOx and WOx solid acids for biomass valorization: interplay of coordination chemistry, acidity, and catalysis</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Acidity</style></keyword><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">catalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Coordination chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">molybdenum oxide</style></keyword><keyword><style  face="normal" font="default" size="100%">tungsten oxide</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">11</style></volume><pages><style face="normal" font="default" size="100%">13603-13648</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Supported molybdenum oxide (MoOx) and tungsten oxide (WOx) materials are a vital class of solid acid catalysts for the chemical industry because of their nontoxic nature, strong acidity, remarkable stability in water, hydrogen, and oxygen atmospheres, and excellent reusability performance. These fascinating solid acids play a pivotal role in developing sustainable catalytic routes for renewable biomass processing to produce value-added fuels, chemicals, and platform molecules. The coordination chemistry of MoOx and WOx on the support materials (oxides, carbons, or zeolites) controls their acidic strength, active site accessibility, and catalytic activity. Hence, significant efforts have been made toward optimizing the conditions used for catalyst synthesis and biomass processing to tune the coordination chemistry of MoOx and WOx with the substrate molecules and, thus, their acid-activity/selectivity performance. This Review provides a comprehensive overview of supported MoOx and WOx solid acids for biomass valorization. The importance of the biomass and the role of solid acids for biomass valorization were emphasized, followed by a brief discussion of supported MoOx and WO(x )solid acids. Afterward, the interplay of coordination chemistry, acidic strength, and catalytic activity of supported MoOx and WOx solid acids was discussed. Finally, their catalytic applications for the valorization of several biomass substrates and their derivatives were summarized. This Review will provide valuable insights for developing advanced supported WOx and MoOx solid acids for catalytic biomass valorization and other challenging acid-catalyzed processes.</style></abstract><issue><style face="normal" font="default" size="100%">21</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">13.084</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singh, Dheerendra</style></author><author><style face="normal" font="default" size="100%">Jogdand, Shunottara M.</style></author><author><style face="normal" font="default" size="100%">Devi, R. Nandini</style></author><author><style face="normal" font="default" size="100%">Dhepe, Paresh L.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Continuous flow hydrodeoxygenation of lignin-derived guaiacol to cyclohexanol over durable Al2O3 hollow fiber supported co catalyst</style></title><secondary-title><style face="normal" font="default" size="100%">ChemCatChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">Carbon</style></keyword><keyword><style  face="normal" font="default" size="100%">Co/Al2O3</style></keyword><keyword><style  face="normal" font="default" size="100%">Cyclohexanol</style></keyword><keyword><style  face="normal" font="default" size="100%">lignin</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">17</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	The drive to decarbonize the chemical, oil, and gas industries through use of bio-derived resources is intensifying. This study focuses on converting lignin-derived phenolic compounds into cyclohexanol, a precursor for adipic acid production. The alumina hollow fiber supported cobalt catalyst (5Co/AHF@capillary) prepared by capillary action method was found to consist cobalt in both metallic and +delta oxidation states. Initial tests in a batch-mode reactor showed promising results, with 5Co/AHF@capillary catalyst demonstrating catalytic activity comparable to Ru/Al2O3 systems (225 degrees C, 1 MPa H-2, 4 h), achieving similar to 86% cyclohexanol yield in guaiacol hydrodeoxygenation reactions. The catalytic system was then adapted for continuous flow reactors under milder conditions (300 degrees C, 2.5 MPa H-2, 18 mL min(-1)), resulting in 83% guaiacol conversion and 74% cyclohexanol yield. The durability of the catalyst was checked for &amp;gt;80 h and results claim that catalyst was active in yielding consistent results. The roles of catalyst preparation method, hydrogen pressure, solvent, WHSV were thoroughly checked and discussed.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">17</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	3.9&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Paul, Sharon</style></author><author><style face="normal" font="default" size="100%">Joseph, Anto</style></author><author><style face="normal" font="default" size="100%">Hridhya, P. D.</style></author><author><style face="normal" font="default" size="100%">Badawi, Michael</style></author><author><style face="normal" font="default" size="100%">Ajithkumar, T. G.</style></author><author><style face="normal" font="default" size="100%">Parameswaranpillai, Jyotishkumar</style></author><author><style face="normal" font="default" size="100%">Asrofi, Mochamad</style></author><author><style face="normal" font="default" size="100%">Dominic, C. D. Midhun</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Extraction of highly crystalline and thermally stable cellulose nanofiber from Heliconia psittacorum L.f. leaves</style></title><secondary-title><style face="normal" font="default" size="100%">International Journal of Biological Macromolecules</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">Nanocellulose</style></keyword><keyword><style  face="normal" font="default" size="100%">Waste to resource</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">308</style></volume><pages><style face="normal" font="default" size="100%">142264</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Extracting cellulose nanofibers (CNF) from agro-waste is one of the promising and practical ways to develop sustainable nanocomposites. In this study, cellulose nanofibers were extracted from the leaves of Heliconia psittacorum for the first time. The combination of oxalic acid hydrolysis (5 wt%) and steam explosion was used for the isolation of CNF from the leaves of Heliconia psittacorum. The structural and chemical features of the prepared CNF were analyzed using various techniques, including Fourier Transform Infrared Spectroscopy (FTIR), Solid state 13C Nuclear Magnetic Resonance Spectroscopy (13C NMR), Scanning Electron Microscopy (SEM), Energy Dispersive X ray analysis (EDX), Transmission electron Microscopy (TEM), X-Ray Diffraction (XRD) and Thermogravimetric analysis (TGA). TEM micrographs reported 15 to 40 nm diameter for the nanofibers synthesized. XRD analysis reported 91 % crystallinity index for CNF, whereas that of the untreated sample was 76 %. The maximum degradation of the CNF is reported at 355 degrees C, exceeds the untreated sample (316 degrees C). The tensile strength of the CNF derived paper was found to be 23 MPa. The recovered nanocellulose can be further utilized for various applications such as the automobile industry for developing lightweight parts, biosensors, super capacitors, absorption of greenhouse gases, wastewater treatment, and packaging applications.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	5.2&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Gode, Nilesh G.</style></author><author><style face="normal" font="default" size="100%">Nagpure, Atul S.</style></author><author><style face="normal" font="default" size="100%">Rewatkar, Suresh B.</style></author><author><style face="normal" font="default" size="100%">Bhagat, Shailesh K.</style></author><author><style face="normal" font="default" size="100%">Deshmukh, Ganpat D.</style></author><author><style face="normal" font="default" size="100%">Saini, Ajay</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synergistic effect of acidic-basic features of copper-doped layered double hydroxides nanocatalysts in valorization of biomass-derived furfural to biofuels</style></title><secondary-title><style face="normal" font="default" size="100%">ChemPlusChem</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Aldol condensation</style></keyword><keyword><style  face="normal" font="default" size="100%">biofuels</style></keyword><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">nanocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">synergistic effect</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">90</style></volume><pages><style face="normal" font="default" size="100%">e202500416</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Valorization of biomass-derived chemicals into high-quality compounds and biofuels is enormously fundamental to diminish dependence on fossil-based resources. Furfural is a bio-based valuable compound which can be proficiently upgraded to 4-(2-furyl)-3-buten-2-one (FAc) and 1,4-pentadiene-3-one, 1,5-di-2-furanyl (F 2 Ac) via aldol condensation of furfural with acetone. In the present work, efficient Cu-doped Mg-Al layered double hydroxides (LDH) nanocatalysts are fabricated by coprecipitation and are exploited for furfural conversion to obtained FAc and F 2 Ac. The structure-activity relationship is scrutinized by characterizing fresh and spent nanocatalysts via numerous techniques. The good correlation between the amount of weak acidic-weak basic catalytic sites and nanocatalysts performance is established. The superior performance of Cu-0.1 nanocatalyst (Cu-content = 1.85 wt%) in aldol condensation is attributed to the presence of optimum weak acidic sites (0.21 mmol g-1) and weak basic sites (0.36 mmol g-1), synergistic acidic-basic effect, nano-sized Cu(OH) 2 nanoparticles (1.6 nm), high BET surface area (181 m2 g-1), and mesoporous architecture of material. Cu-0.1 nanocatalyst delivered 98% FAc selectivity with 100% furfural conversion at 85 degrees C. Furthermore, at 100 degrees C, the nanocatalyst gives 55% F 2 Ac selectivity with 73% furfural conversion. The catalyst displays good recyclability (7 recycles) and stability. Plausible mechanistic pathway for transformation of furfural to FAc and F 2 Ac is proposed.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">12</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	2.8&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Jana, Jayasmita</style></author><author><style face="normal" font="default" size="100%">Chowdhury, Somnath</style></author><author><style face="normal" font="default" size="100%">Saha, Avishek</style></author><author><style face="normal" font="default" size="100%">Kang, Sung Gu</style></author><author><style face="normal" font="default" size="100%">Hur, Seung Hyun</style></author><author><style face="normal" font="default" size="100%">Gopinath, Chinnakonda S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Concurrent glycerol oxidation and hydrogen production on Ce-Co oxide/carbon for sustainable biomass valorization</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Engineering Journal</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Amorphous carbon</style></keyword><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">electrocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">energy conversion</style></keyword><keyword><style  face="normal" font="default" size="100%">green hydrogen</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">535</style></volume><pages><style face="normal" font="default" size="100%">175707</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Integrating glycerol oxidation with water electrolysis offers a sustainable route for hydrogen production while enabling concurrent generation of industrially relevant C1-C3 value-added materials. This system replaces kinetically sluggish oxygen evolution reaction (OER) simultaneously delivering H-2 at the cathode with high turnover frequency, thereby lowering the overall cell voltage and enabling the valorization of glycerol, a major by-product of the biodiesel industry. However, the development of an efficient bifunctional electrocatalysts capable of driving cathodic as well as anodic half-cell reactions remains a key challenge. Herein, we present a cerium-cobalt oxide composite modified with an amorphous carbon layer (Ce,Co-O/C) as an effective bifunctional catalyst for glycerol-assisted water electrolysis. The interfacial electron distribution across the Co-Ce oxide heterojunction generated abundant redox-active sites and accelerates reaction kinetics, while the conductive carbon layer facilitates rapid charge transfer and imparts improved stability. Consequently, the Ce, Co-O/C catalyst exhibited high formate selectivity at 1.4 V (vs RHE) at room temperature and delivers a low cell voltage of 1.90 V at 100 mA cm(-2) in a symmetric Ce,Co-O/C vertical bar vertical bar Ce,Co-O/C system, maintaining operational stability over 100 h. This work provides a promising interface-engineering for designing self-supported bifunctional electrocatalysts toward integrated biomass assisted co-electrolysis systems.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	13.2&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Chauhan, Inderjeet</style></author><author><style face="normal" font="default" size="100%">Patra, Kshirodra Kumar</style></author><author><style face="normal" font="default" size="100%">Vijay, Pothoppurathu M.</style></author><author><style face="normal" font="default" size="100%">Nalajala, Naresh</style></author><author><style face="normal" font="default" size="100%">Mehta, Shweta</style></author><author><style face="normal" font="default" size="100%">Joshi, Kavita</style></author><author><style face="normal" font="default" size="100%">Ravindranathan, Sapna</style></author><author><style face="normal" font="default" size="100%">Gopinath, Chinnakonda S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Potential tuneable glucose oxidation to selective C6 molecules and CC cleavage, and parallel green H2 production: sustainable high current density electrolysis</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Engineering Journal</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">biomass valorization</style></keyword><keyword><style  face="normal" font="default" size="100%">electrocatalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">energy conversion</style></keyword><keyword><style  face="normal" font="default" size="100%">Sustainability</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">529</style></volume><pages><style face="normal" font="default" size="100%">172633</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Current study elucidates the electrocatalytic efficacy of palladium-nanocubes (Pd-NCs) for the selective oxidation of glucose to value-added chemicals with concomitant hydrogen evolution. The Pd-NC catalyst demonstrated exceptional activity and product selectivity, achieving nearly quantitative glucose conversion (&amp;gt;99 %) with high gluconic and glucaric acid yield at low anodic overpotential (0.6 V vs. RHE) in alkaline electrolyte. At not-so-high elevated potentials (1.2 V vs. RHE), oxidative CC scission prevails, yielding shorter-chain carboxylates along with C6-acids. Reaction products are thoroughly characterized and quantitatively estimated by NMR spectral methods; NMR methods also provide CC cleavage and mechanistic pathways of glucose to various products. Complementary DFT calculations delineate the thermodynamic favorability of glucose adsorption on Pd-NC surfaces (-1.83 eV) and the exergonic oxidation pathway under applied bias, corroborating experimental product distributions. In a two-electrode electrolyzer, Pd-NC anode paired with Pt/C and Ni2P cathode demonstrates 100 mA/cm(2) at 0.99 V and 1.37 V, respectively, with 48 % reduction in energy input (26.6 kWh/kg H-2) compared to conventional alkaline electrolysis; critically, H-2 production energy is lower than the usable energy (33.3 kWh/kg H-2). Sustainable chronopotentiometric assays confirm sustainability (similar to 140 h) in alkaline as well as saline electrolytes, underscoring the system's resilience against chloride-mediated corrosion. Present work establishes a proof of concept for integrated biomass-component valorization and carbon-negative green hydrogen production, merging atomic-level mechanistic insights with scalable reactor design. Optimization of reaction parameters, including potential tuning, reaction temperature and electrolyte engineering, offers a compelling strategy to further enhance C6 and fragmented product selectivity and overall system efficiency.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	13.2&lt;/p&gt;
</style></custom4></record></records></xml>