<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Chavan, Subhash P.</style></author><author><style face="normal" font="default" size="100%">Chittiboyina, A. G.</style></author><author><style face="normal" font="default" size="100%">Ramakrishna, G.</style></author><author><style face="normal" font="default" size="100%">Tejwani, R. B.</style></author><author><style face="normal" font="default" size="100%">Ravindranathan, T.</style></author><author><style face="normal" font="default" size="100%">Kamat, Subhash K.</style></author><author><style face="normal" font="default" size="100%">Rai, B.</style></author><author><style face="normal" font="default" size="100%">Sivadasan, L.</style></author><author><style face="normal" font="default" size="100%">Balakrishnan, K.</style></author><author><style face="normal" font="default" size="100%">Ramalingam, S.</style></author><author><style face="normal" font="default" size="100%">Deshpande, V. H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Unusual stereochemical outcome of radical cyclization: synthesis of (+)-biotin</style></title><secondary-title><style face="normal" font="default" size="100%">Tetrahedron</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">biotin</style></keyword><keyword><style  face="normal" font="default" size="100%">exocyclization</style></keyword><keyword><style  face="normal" font="default" size="100%">radical cyclization</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2005</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">39</style></number><publisher><style face="normal" font="default" size="100%">PERGAMON-ELSEVIER SCIENCE LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">61</style></volume><pages><style face="normal" font="default" size="100%">9273-9280</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;An enantioselective synthesis of (+)-biotin 1 starting from naturally available cysteine is described. The key steps are the unusual stereochemical outcome of radical cyclization of compound 10 to prepare 5,5-fused system 11, and the introduction of C4-sidechain at C-6 in 13 via a Grignard reaction. (c) 2005 Elsevier Ltd. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">39</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.645</style></custom4></record></records></xml>