<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Yadav, Poonam</style></author><author><style face="normal" font="default" size="100%">Das, Anoushka K.</style></author><author><style face="normal" font="default" size="100%">Torris, Arun</style></author><author><style face="normal" font="default" size="100%">Wasnik, Kundan</style></author><author><style face="normal" font="default" size="100%">Koppisetti, Heramba Venkata Sai Rama Murthy</style></author><author><style face="normal" font="default" size="100%">Pol, Vilas G.</style></author><author><style face="normal" font="default" size="100%">Shelke, Vilas</style></author><author><style face="normal" font="default" size="100%">Shelke, Manjusha</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Wide temperature enhanced sodium storage in tailored, sustainable sodiophilic biphasic N-doped carbon</style></title><secondary-title><style face="normal" font="default" size="100%">Materials Today Chemistry </style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Full-cell</style></keyword><keyword><style  face="normal" font="default" size="100%">Low and elevated temperatures</style></keyword><keyword><style  face="normal" font="default" size="100%">Na metal host</style></keyword><keyword><style  face="normal" font="default" size="100%">Polymer-derived carbon</style></keyword><keyword><style  face="normal" font="default" size="100%">Sodium-ion battery</style></keyword><keyword><style  face="normal" font="default" size="100%">X-ray tomography</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2024</style></year><pub-dates><date><style  face="normal" font="default" size="100%">APR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">37</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Alternative to Li-ion batteries(LIB), Na-ion batteries (NIB) and Na metal batteries (NMB) are gaining significant attention due to their low cost, abundance, and safety. By modulating microstructural properties such as graphitization, heteroatom doping, surface-rich functional groups, and interlayer d-spacing, Na-ion storage in NIB and Na plating/striping in NMB can be ameliorated. This study reports sodiophilic N-doped polymer-derived carbon (PDC) as an anode for NIB and host for Na metal in NMB. As NIB anode, PDC provides a storage capacity of 173 mAh g- 1 at 1 A g- 1 in half-cell and 84 mAh g- 1 at 1C (1C = 128 mAhg- 1) in full-cell with Na3V2(PO4)2F3 (NVPF) cathode. As Na metal anode (NMA) host, a high columbic efficiency (C.E.) of 99.45% for over 1000 cycles at 6 mA cm- 2_4 mAh cm-2 is obtained. Furthermore, fascinating wide temperature (50 degrees C and -20 degrees C) sodiumion storage is successfully demonstrated by PDC. Advanced X-ray photoelectron spectroscopy (XPS) confirmed the formation of stable and uniform solid electrolyte interphase (SEI) composed of inorganic and organic components, X-ray microtomography confirmed uniform Na plating throughout the volume of the electrode analogous to Brunauer-Emmett-Teller (BET) surface area, Raman spectroscopy, X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) results. A sustainable and scalable promising biphasic NIB anode and sodiophilic host for Na metal was possible due to larger d-spacing, partial graphitization, high mesoporosity, N-doping, presence of surface functional groups, better charge transfer, and diffusion properties.&lt;/p&gt;
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