<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Sen, Anirban</style></author><author><style face="normal" font="default" size="100%">Kumar, Rohit</style></author><author><style face="normal" font="default" size="100%">Tewari, Tanuja</style></author><author><style face="normal" font="default" size="100%">Gonnade, Rajesh G.</style></author><author><style face="normal" font="default" size="100%">Chikkali, Samir H.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Iron-catalyzed alkoxylation, dehydrogenative-polymerization and tandem hydrosilylative-alkoxylation</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry- a european journal </style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">alkoxylation</style></keyword><keyword><style  face="normal" font="default" size="100%">dehydrogenative polymerization</style></keyword><keyword><style  face="normal" font="default" size="100%">earth abundant catalysts</style></keyword><keyword><style  face="normal" font="default" size="100%">hydrosilylative-alkoxylation</style></keyword><keyword><style  face="normal" font="default" size="100%">Iron Catalyst</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">29</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Alkoxylation, hydrosilylative-alkoxylation, and dehydrogenative-polymerization are some of the most widely used transformations in synthetic chemistry. However, these transformations are traditionally catalyzed by precious, and rare late-transition metals. Presented here is a molecularly defined iron complex that catalyzes alkoxylation, tandem hydrosilylative-alkoxylation, and dehydrogenative polymerization of silanes under mild conditions. The iron complex [Fe(CO)(4)(H)(SiPh3)] 1 catalyzes a direct Si-O coupling reaction between an array of silanes and alcohols to produce desired alkoxysilanes in excellent yield, with H-2 as the only byproduct. The iron catalyst tolerates various functional groups and provides access to 20 alkoxysilanes, including essential molecules such as &amp;amp; beta;-citronellol and cholesterol. Further, complex 1 catalyzes the polymerization of renewable diol and silane monomer to produce a renewable and degradable poly(isosorbide-silyl ether). Remarkably, complex 1 catalyzes a tandem hydrosilylative-alkoxylation of alkynes under mild conditions to yield unsaturated silyl ethers. The synthetic utility has been demonstrated by gram-scale alkoxylation and hydrosilylative-alkoxylation reactions.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">48</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p _ngcontent-jbo-c285=&quot;&quot; class=&quot;flex-justify-space-between header-width flex-display-align-center cdx-right-panel-main&quot; data-ta=&quot;jcrSidenav-1-main-header&quot; dir=&quot;auto&quot;&gt;Foreign&lt;/p&gt;
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</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;4.3&lt;/p&gt;
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