<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Singh, A</style></author><author><style face="normal" font="default" size="100%">Sikder, N</style></author><author><style face="normal" font="default" size="100%">Sikder, AK</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Improved synthesis of an energetic material, 1,3,3-trinitroazetidine (TNAZ) exploiting 2-iodoxy benzoic acid (IBX) as an oxidising agent</style></title><secondary-title><style face="normal" font="default" size="100%">Indian Journal of Chemistry Section B - Organic Chemistry including Medicinal Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">2-iodoxy benzoic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">insensiive munitions</style></keyword><keyword><style  face="normal" font="default" size="100%">oxidative nitrolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">oximination</style></keyword><keyword><style  face="normal" font="default" size="100%">strained ring</style></keyword><keyword><style  face="normal" font="default" size="100%">synthesis</style></keyword><keyword><style  face="normal" font="default" size="100%">trinitroazetidine</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2005</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">12</style></number><publisher><style face="normal" font="default" size="100%">NATL INST SCIENCE COMMUNICATION</style></publisher><pub-location><style face="normal" font="default" size="100%">DR K S KRISHNAN MARG, NEW DELHI 110 012, INDIA</style></pub-location><volume><style face="normal" font="default" size="100%">44</style></volume><pages><style face="normal" font="default" size="100%">2560-2563</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Tetrahydropyranyl protected 1,3-dihalo-2-propanol reacts with p-toluene sulfonamide in the presence of K2CO3 to give corresponding N-p-tosyl-3-azetidinol. Deprotection and oxidation with iodoxy benzoic acid followed by oximation of N-p-tosyl-3-azetidinone readily affords the corresponding azetidine oxime in almost quantitative yield. The subsequent oxidative nitrolysis of oxime gives 1,3,3-trinitroazetidine (TNAZ) through a new sequence of reactions with excellent purity (&amp;gt; 99%) and moderate yield (40%).&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">12</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Indian&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">0.471</style></custom4></record></records></xml>