<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Joseph, Trissa</style></author><author><style face="normal" font="default" size="100%">Shanbhag, G. V.</style></author><author><style face="normal" font="default" size="100%">Halligudi, Shivappa B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Copper(II) ion-exchanged montmorillonite as catalyst for the direct addition of N-H bond to CC triple bond</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Molecular Catalysis A - Chemical</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">alkyne</style></keyword><keyword><style  face="normal" font="default" size="100%">Aniline</style></keyword><keyword><style  face="normal" font="default" size="100%">Catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">hydroamination</style></keyword><keyword><style  face="normal" font="default" size="100%">K-10 montmorillonite clay</style></keyword><keyword><style  face="normal" font="default" size="100%">phenyl acetylene</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2005</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1-2</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">236</style></volume><pages><style face="normal" font="default" size="100%">139-144</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;An efficient synthesis of phenyl-(1-phenylethylidene)amine using copper-exchanged montmorillonite clay (Cu K-10) is demonstrated. The catalyst was characterized using UV-vis, XRD, BET surface area measurements, pyridine adsorption etc. The XRD and surface area measurement show that the structural characteristics of the support montmorillonite K-10 (K-10) are preserved after Cu exchange. The hydroamination of phenyl acetylene with aniline was carried out in toluene under reflux condition in N-2 atmosphere at 393 K. The reaction is highly regio-selective for only Markovnikoff's addition of an-tine to CC multiple bond and proceeded smoothly to completion. The reaction conditions were optimized to obtain complete conversion with respect to phenyl acetylene. Reaction data showed that the activity of the catalyst in hydroamination reaction is greater at higher reaction temperatures and nonpolar solvents and NZ pressure promotes the reaction drastically. (c) 2005 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1-2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">3.958</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Joseph, Trissa</style></author><author><style face="normal" font="default" size="100%">Shanbhag, G. V.</style></author><author><style face="normal" font="default" size="100%">Sawant, D. P.</style></author><author><style face="normal" font="default" size="100%">Halligudi, Shivappa B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Chemoselective anti-Markovnikov hydroamination of alpha,beta-ethylenic compounds with amines using montmorillonite clay</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Molecular Catalysis A-Chemical</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">alpha</style></keyword><keyword><style  face="normal" font="default" size="100%">amines</style></keyword><keyword><style  face="normal" font="default" size="100%">anti-Markovnikov addition product</style></keyword><keyword><style  face="normal" font="default" size="100%">beta-ethylenic compounds</style></keyword><keyword><style  face="normal" font="default" size="100%">chemo-selective</style></keyword><keyword><style  face="normal" font="default" size="100%">hydroamination</style></keyword><keyword><style  face="normal" font="default" size="100%">K-10 montmorillonite clay</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1-2</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">250</style></volume><pages><style face="normal" font="default" size="100%">210-217</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The catalytic activity of montmorillonite clays as a catalyst for the hydroamination of alpha,beta-ethylenic compounds with amines was tested. Aniline and substituted amines reacted with alpha,beta-ethylenic compounds in the presence of catalytic amount of commercially available clay to afford exclusively anti-Markovnikov adduct in excellent yields. Aniline reacted with ethyl acrylate to yield only anti-Markovnikov adduct N-[2-(ethoxycarbonyl)ethyl] aniline (mono-addition product). No Markovnikov adduct (N-[1-(ethoxycarbonyl)ethyl]aniline and double addition product N,N-bis[2-(ethoxycarbonyl)ethyl]aniline were formed under selected reaction conditions. For a better exploitation of the catalytic activity in terms of increased activity and improved selectivity for the mono-addition product, the reaction parameters were optimized in terms of temperature, solvent, reactant mole ratio. Under optimized reaction conditions, montmorillonite clay K-10 showed a superior catalytic performance in the hydroamination of ethyl acrylate with aniline with a conversion of aniline to mono-addition product (almost 100% chemoselectivity) with a high rate constant 0.3414 min(-1) compared to the reported protocols. The dependence of conversion of aniline over different types of montmorillonite clays (K-10, K-20, K-30, Al-Pillared clay and untreated clay) has also been discussed. The activities of clay for the hydroamination of different aromatic and aliphatic amines have also been investigated. Under harsh reaction conditions (increased temperature and long reaction time) small amounts of di-addition products were observed. The kinetics data has been interpreted using the initial rate approach model. (c) 2006 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1-2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">3.958</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Shanbhag, Ganapati V.</style></author><author><style face="normal" font="default" size="100%">Joseph, Trissa</style></author><author><style face="normal" font="default" size="100%">Halligudi, Shivaraj B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Copper(II) ion exchanged A1SBA-15: a versatile catalyst for intermolecular hydroamination of terminal alkynes with aromatic amines</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">A1SBA-15</style></keyword><keyword><style  face="normal" font="default" size="100%">addition</style></keyword><keyword><style  face="normal" font="default" size="100%">alkyne</style></keyword><keyword><style  face="normal" font="default" size="100%">Amine</style></keyword><keyword><style  face="normal" font="default" size="100%">Copper catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">heterogeneous</style></keyword><keyword><style  face="normal" font="default" size="100%">hydroamination</style></keyword><keyword><style  face="normal" font="default" size="100%">ion exchange</style></keyword><keyword><style  face="normal" font="default" size="100%">Mesoporous</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2007</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">2</style></number><publisher><style face="normal" font="default" size="100%">ACADEMIC PRESS INC ELSEVIER SCIENCE</style></publisher><pub-location><style face="normal" font="default" size="100%">525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA</style></pub-location><volume><style face="normal" font="default" size="100%">250</style></volume><pages><style face="normal" font="default" size="100%">274-282</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The hydroarnination reaction offers a very attractive route for the synthesis of alkylated amines and their derivatives with no byproduct formation. AISBA-15 was synthesized by isomorphous substitution of aluminum into the framework of SBA-15, which induces the Bronsted acid sites, and these were exchanged with metal ions such as Cu2+, Zn2+, and Pd2+. The catalysts were characterized by XRD, N-2-sOrption, SEM, TEM, acidity measurements by FT-IR pyridine adsorption, H-2-TPR, (27)AI MAS NMR, and Si-29 MAS NMR. Hydroamination of phenylacetylene (PhAc) with 2,4-xylidine has been used as a test reaction, which gave N-(1-phenylethylidene)-2,4-dimethylaniline with no byproduct formation. CuAlSBA-15 and CuAIMCM-41 showed around three times greater activity in hydroamination of PhAc compared with Cu-clay and Cu-beta, due to the moderate Lewis acidity of Cu2+ present in mesoporous supports. The performance of the CuAlSBA-15 was also determined with different alkynes and amines to evaluate the catalyst's general applicability in hydroamination reactions. (c) 2007 Elsevier Inc. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">7.354</style></custom4></record></records></xml>