<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mathew, Nevin T.</style></author><author><style face="normal" font="default" size="100%">Khaire, S.</style></author><author><style face="normal" font="default" size="100%">Mayadevi, S.</style></author><author><style face="normal" font="default" size="100%">Jha, Ratnesh Kumar</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Rearrangement of allyl phenyl ether over Al-MCM-41</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Al-MCM-41</style></keyword><keyword><style  face="normal" font="default" size="100%">allyl phenyl ether</style></keyword><keyword><style  face="normal" font="default" size="100%">Claisen rearrangement</style></keyword><keyword><style  face="normal" font="default" size="100%">Mesoporous material</style></keyword><keyword><style  face="normal" font="default" size="100%">molecular rearrangement</style></keyword><keyword><style  face="normal" font="default" size="100%">Solid acids</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2005</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><publisher><style face="normal" font="default" size="100%">ACADEMIC PRESS INC ELSEVIER SCIENCE</style></publisher><pub-location><style face="normal" font="default" size="100%">525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA</style></pub-location><volume><style face="normal" font="default" size="100%">229</style></volume><pages><style face="normal" font="default" size="100%">105-113</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Claisen rearrangement of allyl phenyl ether to o-allylphenol and a dihydrobenzofuran derivative was investigated over MCM-41 with different Si/Al ratios. Higher aluminum content, higher reaction temperatures, and longer run duration favor the formation of the ring compound 2,3-dihydro-2-methyl benzofuran. There is a close relationship between acidity and conversion, which suggests that the reaction occurs inside the large pores of MCM-41. The influence of temperature and catalyst Si/Al ratio on the reaction are examined by kinetic analysis, under the assumption of a first-order consecutive reaction. (C) 2004 Elsevier Inc. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">7.354</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Wagholikar, S. G.</style></author><author><style face="normal" font="default" size="100%">Mayadevi, S.</style></author><author><style face="normal" font="default" size="100%">Jacob, Nalini E.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Claisen rearrangement of allyl phenyl ether over zeolites beta, mordenite and Y</style></title><secondary-title><style face="normal" font="default" size="100%">Microporous and Mesoporous Materials</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">allyl phenyl ether</style></keyword><keyword><style  face="normal" font="default" size="100%">allylphenol</style></keyword><keyword><style  face="normal" font="default" size="100%">Benzofuran</style></keyword><keyword><style  face="normal" font="default" size="100%">Claisen rearrangement</style></keyword><keyword><style  face="normal" font="default" size="100%">zeolites</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1-3</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">95</style></volume><pages><style face="normal" font="default" size="100%">8-16</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The Claisen rearrangement of allyl phenyl ether (APE) to o-allylphenol was investigated over zeolites beta (BEA), mordenite (MOR) and Y (FAU) with different Si/Al ratios. Over the zeolite catalysts, the allylphenol cyclized to produce 2,3-dihydro-2-methyl benzofuran. Larger catalyst loading, higher reaction temperatures and longer run duration favored the formation of the ring compound. Conversion was small over MOR and FAU although they possessed higher acidity (as measured by the temperature programmed desorption of ammonia) compared to BEA. Studies using BEA revealed that the nature of the solvent influenced the reaction rate. The order of reactivity in the solvents was, benzene &amp;gt; EDC (1,2-dichloroethane) &amp;gt; toluene &amp;gt; TCE (1, 1,2,2-tetrachloroethane) &amp;gt;&amp;gt; ACN (acetonitrile). The intermediate allylphenol reacted with the aromatic solvents to produce byproducts when benzene and toluene were used as solvents. A kinetic analysis assuming first order series and parallel reactions is presented. (c) 2006 Elsevier Inc. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1-3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">3.349</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Wagholikar, Smita</style></author><author><style face="normal" font="default" size="100%">Mayadevi, S.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Liquid phase alkylation of phenol with 1-octene over large pore zeolites</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Catalysis A-General</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">1-octene</style></keyword><keyword><style  face="normal" font="default" size="100%">alkyl phenols</style></keyword><keyword><style  face="normal" font="default" size="100%">Alkylation</style></keyword><keyword><style  face="normal" font="default" size="100%">phenol</style></keyword><keyword><style  face="normal" font="default" size="100%">zeolites</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">309</style></volume><pages><style face="normal" font="default" size="100%">106-114</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;A comparative study is presented of the liquid phase alkylation of phenol with 1-octene over different zeolite catalysts: H-beta (BEA(15)), H-mordenite (MOR(11)) and H-USY (FAU(15)). A wide spectrum of monoalkylated products, identified as isomers of phenyl octyl ether (O-alkylate) and octyl phenol (C-alkylate), was formed in the reaction. The reaction was studied in detail over BEA(15), such studies included the influence of process variables such as temperature, reactant mole ratio, catalyst amount and alkali metal (K) poisoning on its performance in the alkylation reaction. A kinetic analysis of the reaction over BEA(15) was also carried out assuming a second order parallel reaction mechanism. The activity of the different catalysts for the reaction followed the order: BEA(15) &amp;gt; FAU(15) &amp;gt; MOR(11). The poisoning of BEA(15) with potassium resulted in a decrease in the catalyst activity concomitant with a decrease in the number of strong acid centres in the catalyst. (c) 2006 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">4.012</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Karandikar, Prashant R.</style></author><author><style face="normal" font="default" size="100%">Chandwadkar, Asha J.</style></author><author><style face="normal" font="default" size="100%">Agashe, M.</style></author><author><style face="normal" font="default" size="100%">Ramgir, N. S.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Liquid phase oxidation of alkanes using Cu/Co-perchlorophthalocyanine immobilized MCM-41 under mild reaction conditions</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Catalysis A-General</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Ceramics</style></keyword><keyword><style  face="normal" font="default" size="100%">Electron microscopy</style></keyword><keyword><style  face="normal" font="default" size="100%">electronic materials</style></keyword><keyword><style  face="normal" font="default" size="100%">X-ray diffraction</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">2</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCI LTD</style></publisher><pub-location><style face="normal" font="default" size="100%">THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">297</style></volume><pages><style face="normal" font="default" size="100%">220-230</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;{Amino-functionalized MCM-41 (NH2-MCM-41) was used to immobilize CU/CO-Cl16PC complex, i.e. Cu/Co-AM(PS) for liquid phase oxidation of alkanes under mild reaction conditions. Higher rates of reaction and better catalytic activity values were obtained for Cu/Co-AM(PS) as compared to Cu/Co-Cl16PC grafted on (i) amino-functionalized SiO2 [&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">4.012</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Wagholikar, S. G.</style></author><author><style face="normal" font="default" size="100%">Niphadkar, P. S.</style></author><author><style face="normal" font="default" size="100%">Mayadevi, S.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Acylation of anisole with long-chain carboxylic acids over wide pore zeolites</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Catalysis A-General</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Acylation</style></keyword><keyword><style  face="normal" font="default" size="100%">Anisole</style></keyword><keyword><style  face="normal" font="default" size="100%">decanoic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">hexanoic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">octanoic acid</style></keyword><keyword><style  face="normal" font="default" size="100%">zeolites</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2007</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">2</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">317</style></volume><pages><style face="normal" font="default" size="100%">250-257</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The acylation of anisole with long-chain carboxylic acids (hexanoic, octanoic and decanoic) has been studied over three large pore zeolites-beta (BEA), faujasite (FAU) and mordenite (MOR). The acylation of anisole with the long chain acids produced mainly the ketone (4-methoxy phenyl alkyl ketone) and small amounts of the ester (phenyl alkanoate). The results revealed the reaction to be influenced by the type of zeolite and its Si/Al ratio (acidity) besides the chain length (carbon number) of the carboxylic acid. In the acylation of anisole with hexanoic acid, the activity of the zeolites increased with dealumination as it led to the generation of mesopores that resulted in a decrease in diffusion resistance of the zeolites. The reactivity of the acids in the acylation reaction was found to decrease with increase in the carbon number. The experimental data have been fitted into a pseudo first order kinetic model. (c) 2006 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">4.012</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Surse, P. V.</style></author><author><style face="normal" font="default" size="100%">Wagholikar, S.</style></author><author><style face="normal" font="default" size="100%">Mayadevi, S.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Alkylation of anisole with 1-hexene and 1-hexanol over zeolite H-beta</style></title><secondary-title><style face="normal" font="default" size="100%">Reaction Kinetics Mechanisms and Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Alkylation</style></keyword><keyword><style  face="normal" font="default" size="100%">Anisole</style></keyword><keyword><style  face="normal" font="default" size="100%">H-beta</style></keyword><keyword><style  face="normal" font="default" size="100%">Hexene</style></keyword><keyword><style  face="normal" font="default" size="100%">Hexyl alcohol</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2011</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">2</style></number><publisher><style face="normal" font="default" size="100%">SPRINGER</style></publisher><pub-location><style face="normal" font="default" size="100%">VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">103</style></volume><pages><style face="normal" font="default" size="100%">481-491</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;An examination of the kinetics of the alkylation of anisole with 1-hexene and 1-hexanol to produce alkylates over zeolite H-beta is presented. Anisole alkylation is found to occur by a set of parallel reactions when hexene is used as the alkylating agent. When hexyl alcohol is the alkylating agent, the reaction follows a multi-step parallel-series mechanism to form monoalkylates and dihexylether. With 1-hexene, a group of isomeric alkylates, viz., ortho-2-hexyl anisole (2-OHA), ortho-3-hexyl anisole (3-OHA), para-2-hexyl anisole (2-PHA), and para-3-hexyl anisole (3-PHA) was obtained. With hexanol, the olefin (hexene) and dihexyl ether were obtained additionally. The influence of process parameters like temperature, catalyst quantity, and alkylating agent on reaction behavior is reported.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">1.06</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Reddy, Benjaram M.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author><author><style face="normal" font="default" size="100%">Ramaswamy, A. V.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Special Issue dedicated to Paul Ratnasamy on the occasion of his 70th birthday preface</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Today</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">DEC</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1, SI</style></number><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">198</style></volume><pages><style face="normal" font="default" size="100%">1-2</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><issue><style face="normal" font="default" size="100%">1</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.98
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Banu, M.</style></author><author><style face="normal" font="default" size="100%">Sankaranarayanan, T. M.</style></author><author><style face="normal" font="default" size="100%">Venuvanalingam, P.</style></author><author><style face="normal" font="default" size="100%">Magesh, G.</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hydrogenolysis of sorbitol over Ni, Pt and Ru supported on SBA-15</style></title><secondary-title><style face="normal" font="default" size="100%">Indian Journal of Chemistry. Section A: Inorganic, Physical, Theoretical &amp; Analytical Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">http://nopr.niscair.res.in/handle/123456789/40903</style></url></web-urls></urls><volume><style face="normal" font="default" size="100%">56 </style></volume><pages><style face="normal" font="default" size="100%">226-231</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Hydrogenolysis of sorbitol (15% aqueous solution) has been carried out in a batch reactor over Ni (6 wt%), Pt (1 wt%) and Ru (1 wt%) supported on SBA-15 and carbon coated SBA-15 (SBA-15(C)). For comparison, the three metals have also been supported on activated carbon (AC). The catalysts are characterized by XRD, N-2 and H-2 adsorption measurements. Addition of Ca(OH)(2) to the reaction mixture increases conversion and selectivity for the dihydroxy compounds, 1,2-propanediol (PD) and ethylene glycol (EG). Based on yield of dihydric alcohols (PD+EG), the performance of the catalysts at 220 degrees C and 60 bar in the presence of Ca(OH)(2) is in the order: Ru-AC similar to Ru-SBA-15(C) &gt; Ru-SBA-15 similar to Ni-SBA-15, the yields being 40, 39, 31 and 29 wt%, respectively.</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Indian</style></custom3><custom4><style face="normal" font="default" size="100%">0.566</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kandasamy, Thirunavukkarasu</style></author><author><style face="normal" font="default" size="100%">Banu, Marimuthu</style></author><author><style face="normal" font="default" size="100%">Shanthi, R. Vijaya</style></author><author><style face="normal" font="default" size="100%">Sivasanker, S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Suitability of different supported Ru, Pt and Ni catalysts for the hydrogenolysis of sorbitol</style></title><secondary-title><style face="normal" font="default" size="100%">Results in Engineering</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2022</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">15</style></volume><pages><style face="normal" font="default" size="100%">100594</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	&amp;nbsp;&lt;/p&gt;
&lt;ul class=&quot;issue-navigation u-margin-s-bottom u-bg-grey1&quot; id=&quot;issue-navigation&quot; style=&quot;box-sizing: border-box; margin-top: 0px; margin-right: 0px; margin-left: 0px; padding-right: 0px; padding-left: 0px; list-style: none; overflow: hidden; font-size: 16px; line-height: 24px; color: rgb(46, 46, 46); font-family: NexusSans, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, sans-serif; margin-bottom: 16px !important; background-color: rgb(245, 245, 245) !important;&quot;&gt;
&lt;/ul&gt;
&lt;div class=&quot;Abstracts u-font-gulliver text-s&quot; id=&quot;abstracts&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; --sd-ui-line-height: calc(1em + 10px); font-size: 0.8rem; line-height: var(--sd-ui-line-height); color: rgb(46, 46, 46); font-family: ElsevierGulliver, Georgia, &amp;quot;Times New Roman&amp;quot;, STIXGeneral, &amp;quot;Cambria Math&amp;quot;, Arial, Helvetica, &amp;quot;Lucida Sans Unicode&amp;quot;, &amp;quot;Microsoft Sans Serif&amp;quot;, &amp;quot;Segoe UI Symbol&amp;quot;, &amp;quot;Arial Unicode MS&amp;quot;, serif !important;&quot;&gt;
	&lt;div class=&quot;abstract author&quot; id=&quot;abs0010&quot; lang=&quot;en&quot; style=&quot;box-sizing: border-box; margin: 0px 0px 8px; padding: 0px;&quot;&gt;
		&lt;div id=&quot;abssec0010&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px;&quot;&gt;
			&lt;p id=&quot;abspara0010&quot; style=&quot;box-sizing: border-box; margin: 0px 0px 16px; padding: 0px;&quot;&gt;
				In this article, the results of sorbitol&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/engineering/hydrogenolysis&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about hydrogenolysis from ScienceDirect's AI-generated Topic Pages&quot;&gt;hydrogenolysis&lt;/a&gt;&amp;nbsp;(15% aq. solution), done in an autoclave reactor, over Ru, Pt and Ni loaded on SBA15, carbon coated SBA15 (SBA15C), activated carbon (AcC), Na–Y, Fly Ash (FA) and hydroxyapatite (HAP) catalysts by our group, were compared to find the best metal-support combinations. The metal loading was 1&amp;nbsp;wt% for Ru and Pt, 6&amp;nbsp;wt% for Ni and the catalysts' preparations were carried out by impregnation of respective salts. The catalysts were characterized with nitrogen and hydrogen adsorption measurements and X-ray diffraction. Addition of a base (Calcium hydroxide) to the reactants' mixture increased the overall conversion and selectivities of the glycols, ethylene glycol (EG) and 1,2-propylene glycol (PG). The catalysts’ performance at 60&amp;nbsp;bar and 220&amp;nbsp;°C with the presence of base (B), evaluated by the yield of glycols (PG&amp;nbsp;+&amp;nbsp;EG), showed the following order:&lt;/p&gt;
			&lt;p id=&quot;abspara0015&quot; style=&quot;box-sizing: border-box; margin: 0px 0px 16px; padding: 0px;&quot;&gt;
				Ni/Na–Y&amp;nbsp;&amp;gt;&amp;nbsp;Ru/AcC&amp;nbsp;∼&amp;nbsp;Ru/SBA15C&amp;nbsp;&amp;gt;&amp;nbsp;Ni/HAP&amp;nbsp;∼&amp;nbsp;Ru/SBA15&amp;nbsp;&amp;gt;&amp;nbsp;Ni/SBA15&amp;nbsp;&amp;gt;&amp;nbsp;Ru/Na–Y&amp;nbsp;&amp;gt;&amp;nbsp;Ni/FA&amp;nbsp;∼&amp;nbsp;Ni/AcC and the yields were 57, 40, 39, 33, 31, 29, 26, 22 and 21&amp;nbsp;wt%, respectively.&lt;/p&gt;
			&lt;p id=&quot;abspara0020&quot; style=&quot;box-sizing: border-box; margin: 0px 0px 16px; padding: 0px;&quot;&gt;
				Na–Y appeared to be the best support, especially for Ni metal; AcC and SBA15C were good supports for Ru and Pt respectively.&amp;nbsp;&lt;a class=&quot;topic-link&quot; href=&quot;https://www.sciencedirect.com/topics/engineering/reusability&quot; style=&quot;box-sizing: border-box; margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-thickness: 1px; text-decoration-color: rgb(46, 46, 46); color: rgb(46, 46, 46); text-underline-offset: 1px;&quot; title=&quot;Learn more about Reusability from ScienceDirect's AI-generated Topic Pages&quot;&gt;Reusability&lt;/a&gt;&amp;nbsp;studies revealed that Ni on HAP was the best catalyst and exhibited only a small deactivation during four runs of loading it.&lt;/p&gt;
			&lt;div&gt;
				&amp;nbsp;&lt;/div&gt;
		&lt;/div&gt;
	&lt;/div&gt;
&lt;/div&gt;
&lt;p&gt;
	&amp;nbsp;&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	NA&lt;/p&gt;
</style></custom4></record></records></xml>