<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Mine, Eiichi</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Ebina, Takeo</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Control of stereoselectivity in 4-tert-butylphenol hydrogenation over a carbon-supported rhodium catalyst by carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">9</style></number><publisher><style face="normal" font="default" size="100%">CHEMICAL SOC JAPAN</style></publisher><pub-location><style face="normal" font="default" size="100%">1-5 KANDA-SURUGADAI CHIYODA-KU, TOKYO, 101-8307, JAPAN</style></pub-location><volume><style face="normal" font="default" size="100%">35</style></volume><pages><style face="normal" font="default" size="100%">1060-1061</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;cis-4-tert-Butylcyclohexanol was obtained with a high cis ratio (cis/(cis + trans) = 0.9) in the hydrogenation of 4-tert-butylphenol over a carbon-supported rhodium catalyst along with hydrochloric acid in supercritical carbon dioxide solvent.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">9</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">1.55</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Mine, Eiichi</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Low temperature hydrogenation of tetralin over supported rhodium catalysts in supercritical carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Catalysis A-General</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">cis-decalin</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogen storage</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogenation</style></keyword><keyword><style  face="normal" font="default" size="100%">Supercritical carbon dioxide</style></keyword><keyword><style  face="normal" font="default" size="100%">supported rhodium catalysts</style></keyword><keyword><style  face="normal" font="default" size="100%">tetralin</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">310</style></volume><pages><style face="normal" font="default" size="100%">194-198</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrogenation of tetralin was studied over supported rhodium catalysts in supercritical carbon dioxide solvent at 333 K. The results were compared with those in an organic solvent and under neat conditions. Higher cis-decalin yield was obtained in supercritical carbon dioxide solvent than under non-supercritical conditions. It was observed that higher hydrogen concentration at the surface in supercritical carbon dioxide solvent led to fast direct hydrogenation of tetralin to cis-decalin; the flipping of the intermediate, octalin, to give trans-decalin could be prevented. (C) 2006 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">4.012</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mine, Eiichi</style></author><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Selective hydrogenation of naphthols to tetralones over supported palladium catalysts in supercritical carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2006</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">7</style></number><publisher><style face="normal" font="default" size="100%">CHEMICAL SOC JAPAN</style></publisher><pub-location><style face="normal" font="default" size="100%">1-5 KANDA-SURUGADAI CHIYODA-KU, TOKYO, 101-8307, JAPAN</style></pub-location><volume><style face="normal" font="default" size="100%">35</style></volume><pages><style face="normal" font="default" size="100%">780-781</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Naphthols were selectively hydrogenated to the corresponding tetralones over supported palladium metal catalysts in super-critical carbon dioxide solvent.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">7</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;</style></custom3><custom4><style face="normal" font="default" size="100%">1.55</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Tetsuka, Hiroyuki</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Stereoselective hydrogenation of tert-butylphenols over charcoal-supported rhodium catalyst in supercritical carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">charcoal-supported rhodium catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">stereoselective hydrogenation</style></keyword><keyword><style  face="normal" font="default" size="100%">supercritical carbon dioxide solvent</style></keyword><keyword><style  face="normal" font="default" size="100%">tert-butylcyclohexanol</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2007</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">1</style></number><publisher><style face="normal" font="default" size="100%">ACADEMIC PRESS INC ELSEVIER SCIENCE</style></publisher><pub-location><style face="normal" font="default" size="100%">525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA</style></pub-location><volume><style face="normal" font="default" size="100%">252</style></volume><pages><style face="normal" font="default" size="100%">57-68</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrogenation of 2-, 3-, and 4-tert-butylphenols was studied over a charcoal- supported rhodium catalyst in supercritical carbon dioxide (scCO(2)) solvent, and the results were compared with those in organic solvents. In the hydrogenation of 4-tert-butylphenol, a higher cis ratio for 4-tert-butylcyclohexanol (0.79) was obtained in scCO(2) (10 MPa) than in 2-propanol (0.70) and cyclohexane (0.64) under similar conditions of hydrogen pressure (2 MPa) and temperature (313 K). In the case of 2-tert-butylphenol, the cis ratio for 2-tert-butylcyclohexanol was as high as 0.95 in both scCO(2) and 2-propanol (hydrogen pressure, 2 MPa; reaction temperature, 313 K). In the case of hydrogenation of 3-tert-butylphenol, the cis ratio decreased with the progression of consecutive hydrogenation of 3-tert-butylcyclohexanone intermediate. In addition, the stereoselectivity to cis-tert-butylcyclohexanols in scCO(2) was improved in the presence of hydrochloric acid. It was found that the protons of hydrochloric acid accelerated the hydrogenation of the intermediates, tert-butylcyclohexanones, to the corresponding cis-tert-butylcyclohexanols. The hydrogenation mechanism of tert-butylphenols, particularly the enhanced selectivity to cis-tert-butylcyclohexanols in scCO(2), is postulated based on the observed reaction profiles. (c) 2007 Elsevier Inc. All rights reserved.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">7.354</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Enhancement of glycerol conversion to acetol in high-temperature liquid water by high-pressure carbon dioxide</style></title><secondary-title><style face="normal" font="default" size="100%">Chemistry Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2008</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">9</style></number><publisher><style face="normal" font="default" size="100%">CHEMICAL SOC JAPAN</style></publisher><pub-location><style face="normal" font="default" size="100%">1-5 KANDA-SURUGADAI CHIYODA-KU, TOKYO, 101-8307, JAPAN</style></pub-location><volume><style face="normal" font="default" size="100%">37</style></volume><pages><style face="normal" font="default" size="100%">926-927</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Dehydration of glycerol to acetol proceeded in high-temperature liquid water at 573 K in a batch reactor. The acetol formation rate increased with an addition of high-pressure carbon dioxide.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">9</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">1.55</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Mine, Eiichi</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Activity and selectivity behavior of 1,2-epoxyethylbenzne hydrogenation in carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Industrial &amp; Engineering Chemistry Research</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2009</style></year><pub-dates><date><style  face="normal" font="default" size="100%">NOV</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">21</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">48</style></volume><pages><style face="normal" font="default" size="100%">9457-9460</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Catalytic hydrogenation of 1,2-epoxyethylbenzene to 2-phenylethanol over charcoal-supported noble metal in carbon dioxide was studied, and the results were compared with those in heptane and methanol. Charcoal-supported palladium and platinum (Pd/C and Pt/C) catalysts were active metal species for the hydrogenation in solvents. The order of activities over palladium and platinum was heptane &amp;lt; carbon dioxide &amp;lt; methanol; however, the formation of dehydroxylated byproduct was suppressed in carbon dioxide solvent. Negative carbon dioxide pressure effect was observed over the Pd/C and Pt/C catalysts in the carbon dioxide solvent.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">21</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.071</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Garade, Ajit C.</style></author><author><style face="normal" font="default" size="100%">Hengne, Amol M.</style></author><author><style face="normal" font="default" size="100%">Deshpande, Tushar N.</style></author><author><style face="normal" font="default" size="100%">Shaligram, Sayali V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Continuous hydroxyalkylation of p-Cresol to 2,2 `-methylenebis(4-Methylphenol) in a fixed bed reactor</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Chemical Engineering of Japan</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2009</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">10</style></number><volume><style face="normal" font="default" size="100%">42</style></volume><pages><style face="normal" font="default" size="100%">782-787</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;{Catalytic activity of various solid acid catalysts is evaluated for the continuous hydroxyalkylation of p-cresol to [&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">10</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">0.442</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kshirsagar, Vikas S.</style></author><author><style face="normal" font="default" size="100%">Garade, Ajit C.</style></author><author><style face="normal" font="default" size="100%">Patil, Kashinath R.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Liquid phase oxidation of p-cresol over cobalt saponite</style></title><secondary-title><style face="normal" font="default" size="100%">Topics in Catalysis</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Co-saponite</style></keyword><keyword><style  face="normal" font="default" size="100%">Liquid phase oxidation</style></keyword><keyword><style  face="normal" font="default" size="100%">p-Cresol</style></keyword><keyword><style  face="normal" font="default" size="100%">p-Hydroxybenzaldehyde</style></keyword><keyword><style  face="normal" font="default" size="100%">XPS</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2009</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUN</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">6-7</style></number><publisher><style face="normal" font="default" size="100%">SPRINGER/PLENUM PUBLISHERS</style></publisher><pub-location><style face="normal" font="default" size="100%">233 SPRING ST, NEW YORK, NY 10013 USA</style></pub-location><volume><style face="normal" font="default" size="100%">52</style></volume><pages><style face="normal" font="default" size="100%">784-788</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Liquid phase oxidation of p-cresol was carried out over a Co-saponite catalyst in a temperature and pressure range of 333-393 K and 20-827 kPa, respectively in n-propanol. Co-saponites with varying cobalt content (5-30%) were prepared and screened among which 13% Co-saponite gave the highest conversion of 92% of p-cresol with 92% selectivity to p-hydroxybenzaldehyde without formation of any non-oxidation products.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">6-7</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.359</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Masuda, Yoshio</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Phase behavior of hydrogenation of 2-tert-butylphenol over a charcoal-supported rhodium catalyst in carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Chemical and Engineering Data</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2009</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">5</style></number><publisher><style face="normal" font="default" size="100%">AMER CHEMICAL SOC</style></publisher><pub-location><style face="normal" font="default" size="100%">1155 16TH ST, NW, WASHINGTON, DC 20036 USA</style></pub-location><volume><style face="normal" font="default" size="100%">54</style></volume><pages><style face="normal" font="default" size="100%">1610-1612</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Catalytic hydrogenation of 2-tert-butyl phenol over a charcoal-supported rhodium catalyst in carbon dioxide solvent at 313 K was studied in a batch reactor. To elucidate the effect of carbon dioxide pressure on the initial rate of reaction, the phase behavior of the ternary (2-tert-butylphenol-carbon dioxide-hydrogen) system was separately observed with a view cell, and the calculations of vapor-liquid equilibrium and compositions in the vapor and liquid phases inside the reactor were carried out using the Peng-Robinson equation of state. The hydrogenation behavior in the carbon dioxide solvent is discussed based on the phase behavior of the ternary system.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">5</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">2.089</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Kinetic analysis of 4-isopropylphenol hydrogenation over activated carbon-supported rhodium catalysts in supercritical carbon dioxide solvent</style></title><secondary-title><style face="normal" font="default" size="100%">Green Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Jan</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">3</style></number><publisher><style face="normal" font="default" size="100%">ROYAL SOC CHEMISTRY</style></publisher><pub-location><style face="normal" font="default" size="100%">THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">14</style></volume><pages><style face="normal" font="default" size="100%">633-638</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrogenation behavior of 4-isopropylphenol to 4-isopropylcyclohexanol over activated carbon-supported rhodium catalysts in supercritical carbon dioxide (scCO(2)) at 313 K was studied in a batch reactor and the results were compared with those in 2-propanol. Higher yields of cis-4-isopropylcyclohexanol were obtained in scCO(2) than in 2-propanol, and the formation of a byproduct, isopropylcyclohexane, was suppressed in scCO(2). The catalyst modification with hydrochloric or phosphoric acid enhanced the yield of cis-4-isopropylcyclohexanol in both scCO(2) and 2-propanol solvents. Kinetic analyses of the reaction profiles revealed higher reaction rates in scCO(2) than those in 2-propanol for the 4-isopropylcyclohexanol formation both by the direct hydrogenation of 4-isopropylphenol and by the consecutive hydrogenation of 4-isopropylcyclohexanone, and also revealed that the addition of hydrochloric acid increased the consecutive hydrogenation rate of 4-isopropylcyclohexanone to cis-4-isopropylcyclohexanol, which reduced the total reaction time needed for the complete hydrogenation of 4-isopropylphenol to 4-isopropylcyclohexanol.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">6.828
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mane, Rasika B.</style></author><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Malawadkar, Atul V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Active sites in modified copper catalysts for selective liquid phase dehydration of aqueous glycerol to acetol</style></title><secondary-title><style face="normal" font="default" size="100%">RSC Advances</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">37</style></number><publisher><style face="normal" font="default" size="100%">ROYAL SOC CHEMISTRY</style></publisher><pub-location><style face="normal" font="default" size="100%">THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND</style></pub-location><volume><style face="normal" font="default" size="100%">3</style></volume><pages><style face="normal" font="default" size="100%">16499-16508</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;We report here the influence of oxides of various metals viz. Ba, Mg, Zr, Zn, Al, and Cr in modified copper catalysts, on the formation of different copper species and acid sites responsible for dehydration of aqueous glycerol to acetol. These catalysts were prepared by a co-precipitation method, among which the catalysts having higher acid strength and predominant Bronsted acidity (Cu-Mg, Cu-Zr and Cu-Al) gave the highest acetol selectivity (76-92%), while the catalysts with lower acidity such as Cu-Zn showed very poor (25%) selectivity to acetol in spite of the highest conversion of 68%. Nevertheless, catalysts exhibiting higher activity and acetol selectivity also showed the presence of metallic Cu confirmed by XRD and XANES-EXAFS characterization. Based on these results, two different catalytic pathways have been proposed highlighting the role of Lewis and Bronsted acidity along with the metal sites in individual steps of glycerol dehydration reaction.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">37</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">3.708
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiyoshi, Norihito</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Effect of carbon dioxide pressure on 4-t-butylphenol hydrogenation activity of supported rhodium catalyst</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of the Japan Petroleum Institute</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">4-t-Butylphenol hydrogenation</style></keyword><keyword><style  face="normal" font="default" size="100%">Carbon dioxide solvent</style></keyword><keyword><style  face="normal" font="default" size="100%">Peng-Robinson equation</style></keyword><keyword><style  face="normal" font="default" size="100%">Rhodium catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">Supercritical fluid</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><number><style face="normal" font="default" size="100%">3</style></number><publisher><style face="normal" font="default" size="100%">JAPAN PETROLEUM INST</style></publisher><pub-location><style face="normal" font="default" size="100%">YOYU-KANDA BLDG. 4F, 1-8-4 KANDASUDA-CHO, CHIYODA-KU, TOKYO, 108-0041, JAPAN</style></pub-location><volume><style face="normal" font="default" size="100%">56</style></volume><pages><style face="normal" font="default" size="100%">165-170</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Hydrogenation of 4-t-butylphenol over an activated carbon-supported rhodium catalyst in carbon dioxide solvent was analyzed based on phase observation with a view cell and calculations of the solubility of 4-t-butylphenol using the Peng-Robinson equation of state as a function of carbon dioxide pressure. The reaction experiments showed that the initial reaction rate of 4-t-butylphenol at 313 K under 2 MPa of hydrogen pressure was increased by the addition of carbon dioxide, especially above a total pressure of 11 MPa. Direct visual observation showed that the solubility of 4-t-butylphenol increased with higher carbon dioxide pressure. The calculations based on the Peng-Robinson equation of state also showed that the solubility of 4-t-butylphenol in the 4-t-butylphenol carbon dioxide hydrogen (2 MPa) system at 313 K significantly increased by addition of carbon dioxide above a total pressure of 11 MPa. We concluded that the increase in the hydrogenation rates was caused by the increased concentration of 4-t-butylphenol substrate in the carbon dioxide solvent.&lt;/p&gt;</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">0.58</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mate, Vivek R.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Heterogeneous Co3O4 catalyst for selective oxidation of aqueous veratryl alcohol using molecular oxygen</style></title><secondary-title><style face="normal" font="default" size="100%">Catalysis Communications</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Co3O4</style></keyword><keyword><style  face="normal" font="default" size="100%">Cyclic voltammogram</style></keyword><keyword><style  face="normal" font="default" size="100%">Liquid phase oxidation</style></keyword><keyword><style  face="normal" font="default" size="100%">Molecular oxygen</style></keyword><keyword><style  face="normal" font="default" size="100%">Veratryl alcohol</style></keyword><keyword><style  face="normal" font="default" size="100%">XPS</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">33</style></volume><pages><style face="normal" font="default" size="100%">66-69</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Nano-structured, spinel Co3O4 catalyst was developed for the aqueous phase oxidation of veratryl alcohol, which showed the highest conversion of 85% with 96% selectivity to veratryl aldehyde. The co-existence of Co3+ and Co2+ species in the octahedral and tetrahedral positions respectively, was confirmed by XPS, cyclic voltammogram, TPR and TPO characterization. The rod-like morphology of Co3O4 catalyst was confirmed by HRTEM. The effects of various reaction parameters namely, catalyst concentration, temperature and partial oxygen pressure on conversion and selectivity patterns were also studied for the oxidation of veratryl alcohol. This catalyst also showed an excellent stability as evidenced by successful reusability for three times. (C) 2012 Published by Elsevier B.V.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">3.32
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Mane, Rasika B.</style></author><author><style face="normal" font="default" size="100%">Patil, S.</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author><author><style face="normal" font="default" size="100%">Rayalu, Sadhana S.</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Influence of carbon based supports on selectivity behavior of diols and propanol in Ru catalyzed glycerol hydrogenolysis</style></title><secondary-title><style face="normal" font="default" size="100%">Applied Catalysis B: Environmental</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">activated carbon</style></keyword><keyword><style  face="normal" font="default" size="100%">Amorphous carbon</style></keyword><keyword><style  face="normal" font="default" size="100%">catalysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Glycerol</style></keyword><keyword><style  face="normal" font="default" size="100%">Glycerol conversions</style></keyword><keyword><style  face="normal" font="default" size="100%">Glycerol hydrogenolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">graphite composites</style></keyword><keyword><style  face="normal" font="default" size="100%">Graphite supports</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogenolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">layered structures</style></keyword><keyword><style  face="normal" font="default" size="100%">Particle size</style></keyword><keyword><style  face="normal" font="default" size="100%">Product distributions</style></keyword><keyword><style  face="normal" font="default" size="100%">Propanediols</style></keyword><keyword><style  face="normal" font="default" size="100%">Propanol</style></keyword><keyword><style  face="normal" font="default" size="100%">Selectivity behavior</style></keyword><keyword><style  face="normal" font="default" size="100%">Structural characteristics</style></keyword><keyword><style  face="normal" font="default" size="100%">Structural effect</style></keyword><keyword><style  face="normal" font="default" size="100%">Structural effects</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2017</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAY</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">204</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Activated carbon (AC) and three graphite materials were studied as supports for Ru catalyzed glycerol hydrogenolysis to propanediols and 1-propanol. Structural characteristics of AC and graphite materials were found to greatly affect the reducibility and particle size of supported Ru and hence, the activity and product distribution in glycerol hydrogenolysis. XRD of graphite materials showed distinctly (002) plane having highly organized layered structure and the peak intensity decreased in the order of Ru/KS150 &amp;gt; Ru/HSAG100 &amp;gt; Ru/KS6 due to decrease in the graphite sheet thickness. In Raman, the intense D band in HSAG100 compared to that in KS6 and KS150 samples indicated its highly amorphous nature or mixed carbon hybridization. Glycerol conversion for Ru on AC was higher than that on graphite and among different graphites, it showed a descending activity order of Ru/KS6 &amp;gt; Ru/HSAG100 &amp;gt; Ru/KS150. The product distribution for AC and HSAG100 supported Ru was similar, giving 1-propanol (45%) alongwith 1,2-propanediol (1,2-PDO) (37%) and 1,3-propanediol (1,3-PDO) (9–11%). For graphite supports, availability of Ru although bigger in size (4–5 nm), would be higher on the surface than in case of AC which formed deep hydrogenolysis products like 1-, 2- propanol, ethanol etc.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">11.698</style></custom4><section><style face="normal" font="default" size="100%">134-146</style></section></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Hiraishi, Yushi</style></author><author><style face="normal" font="default" size="100%">Minakawa, Naohiro</style></author><author><style face="normal" font="default" size="100%">Taniguchi, Kenkichi</style></author><author><style face="normal" font="default" size="100%">Nagasawa, Yoshiyuki</style></author><author><style face="normal" font="default" size="100%">Nanao, Hidetaka</style></author><author><style face="normal" font="default" size="100%">Rode, V, Chandrashekhar</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Hydrogenolysis of benzofuran using aqueous ethanol solution over graphite-supported platinum catalyst</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of the Indian Chemical Society</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Biomass conversion</style></keyword><keyword><style  face="normal" font="default" size="100%">Graphite support</style></keyword><keyword><style  face="normal" font="default" size="100%">Hydrogenolysis</style></keyword><keyword><style  face="normal" font="default" size="100%">platinum catalysts</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2021</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">98</style></volume><pages><style face="normal" font="default" size="100%">100021</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">Graphite-supported platinum catalysts (Pt/G) were highly active for the hydrogenolysis of benzofuran to o-ethylphenol in aqueous ethanol solution at 523 K without using any external hydrogen gas. The hydrogenolysis activities and selectivity to o-ethylphenol in ethanol solution over Pt/G were higher than those with a conventional method using externally supplied hydrogen gas. Both water and ethanol were indispensable for the hydrogenolysis in aqueous ethanol solution at 523 K.</style></abstract><issue><style face="normal" font="default" size="100%">2</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">Indian</style></custom3><custom4><style face="normal" font="default" size="100%">0.284</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Taniguchi, Kenkichi</style></author><author><style face="normal" font="default" size="100%">Kusumawati, Etty N.</style></author><author><style face="normal" font="default" size="100%">Nanao, Hidetaka</style></author><author><style face="normal" font="default" size="100%">Rode, Chandrashekhar V.</style></author><author><style face="normal" font="default" size="100%">Sato, Osamu</style></author><author><style face="normal" font="default" size="100%">Yamaguchi, Aritomo</style></author><author><style face="normal" font="default" size="100%">Shirai, Masayuki</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Conversion of benzyl phenyl ether to monoaromatics in high-temperature aqueous ethanol solution under high-pressure carbon dioxide conditions</style></title><secondary-title><style face="normal" font="default" size="100%">New Journal of Chemistry</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2023</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JUL</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">47</style></volume><pages><style face="normal" font="default" size="100%">12561-12569</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Solvolysis of benzyl phenyl ether (BPE), which is a model compound of lignin ether linkage, was studied in an aqueous ethanol solution, which can be obtained from bioethanol, under high-pressure carbon dioxide conditions. A batch study revealed that BPE solvolysis to monoaromatics (benzyl ethyl ether (BEE), benzyl alcohol (BA), and phenol (Ph)) proceeded in aqueous ethanol solution over 523 K and the addition of high-pressure carbon dioxide enhanced the initial solvolysis rate and suppressed the side reaction (hydrogenolysis to toluene (TL)). The ethanol molar fraction (ethanol-water volume ratio) is the key factor for the solvolysis reaction, and the highest monoaromatic yield of 72.9% (BEE 10.7%, BA 19.3%, Ph 37.9%, and TL 5.1%) was obtained in aqueous ethanol solution (2 cm(3) : 1 cm(3) = water:ethanol) at 598 K for 3 h under a pressure of 18 MPa of carbon dioxide. The solvolysis reaction proceeded continuously to produce monoaromatics with a flow system. A monoaromatic yield of 76.7% (BEE 8.6%, BA 19.7%, Ph 39.6%, and TL 8.9%) was obtained, and the formation rates were 2.7 x 10(-4) mmol min(-1) for BEE, 6.2 x 10(-4) mmol min(-1) for BA, and 12.4 x 10(-4) mmol min(-1) for Ph at 598 K under flowing water (26 mmol min(-1)), ethanol solution (4.1 mmol min(-1)), carbon dioxide (1.2 mmol min(-1)), and BPE (15.6 x 10(-4) mmol min(-1)) under a total pressure of 40 MPa.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">27</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	3.3&lt;/p&gt;
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