<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ghosh, Meena</style></author><author><style face="normal" font="default" size="100%">Vijayakumar, Vidyanand</style></author><author><style face="normal" font="default" size="100%">Kurungot, Sreekumar</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Dendrite growth suppression by Zn2+-integrated nafion ionomer membranes: beyond porous separators toward aqueous Zn/V2O5 batteries with extended cycle life </style></title><secondary-title><style face="normal" font="default" size="100%">Energy Technology</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2019</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">7</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;&lt;span class=&quot;hitHilite&quot;&gt;The&lt;/span&gt; dendritic/irregular &lt;span class=&quot;hitHilite&quot;&gt;growth&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; zinc deposits in &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; anode &lt;span class=&quot;hitHilite&quot;&gt;surface&lt;/span&gt; is often considered as &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; major intricacy limiting &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; lifespan &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;aqueous&lt;/span&gt; zinc-ion &lt;span class=&quot;hitHilite&quot;&gt;batteries&lt;/span&gt;. &lt;span class=&quot;hitHilite&quot;&gt;The&lt;/span&gt; effect &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;separators&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;on&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; evolution &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;surface&lt;/span&gt; morphology &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; anode/cathode is never thoroughly studied. Herein, &lt;span class=&quot;hitHilite&quot;&gt;for&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; first time, &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; efficacy &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Zn2+-integrated&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Nafion&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;ionomer&lt;/span&gt; membrane is demonstrated as &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; separator &lt;span class=&quot;hitHilite&quot;&gt;to&lt;/span&gt; effectively suppress &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;growth&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; irregular zinc deposits in &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; metallic anode &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;an&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;aqueous&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Zn&lt;/span&gt;/&lt;span class=&quot;hitHilite&quot;&gt;V2O5&lt;/span&gt; battery. &lt;span class=&quot;hitHilite&quot;&gt;The&lt;/span&gt; Zn2+-ions coordinated &lt;span class=&quot;hitHilite&quot;&gt;with&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; SO3- moieties in &lt;span class=&quot;hitHilite&quot;&gt;Nafion&lt;/span&gt; result in &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;high&lt;/span&gt; transference number &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; Zn2+ cation, all &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; while facilitating &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;high&lt;/span&gt; ionic conductivity. &lt;span class=&quot;hitHilite&quot;&gt;The&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Zn2+-integrated&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Nafion&lt;/span&gt; membrane enables &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Zn&lt;/span&gt;/&lt;span class=&quot;hitHilite&quot;&gt;V2O5&lt;/span&gt; cell &lt;span class=&quot;hitHilite&quot;&gt;to&lt;/span&gt; deliver &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;high&lt;/span&gt; specific capacity &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; 510 mAh g(-1) at &lt;span class=&quot;hitHilite&quot;&gt;a&lt;/span&gt; current &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; 0.25 &lt;span class=&quot;hitHilite&quot;&gt;A&lt;/span&gt; g(-1), which is close &lt;span class=&quot;hitHilite&quot;&gt;to&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; theoretical capacity &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; anhydrous &lt;span class=&quot;hitHilite&quot;&gt;V2O5&lt;/span&gt; (589 mAh g(-1)). Moreover, &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; same cell exhibits &lt;span class=&quot;hitHilite&quot;&gt;an&lt;/span&gt; excellent cycling stability &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; 88% retention &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; initial capacity even after 1800 charge-discharge cycles, superior &lt;span class=&quot;hitHilite&quot;&gt;to&lt;/span&gt; that &lt;span class=&quot;hitHilite&quot;&gt;of&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;the&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;Zn&lt;/span&gt;/&lt;span class=&quot;hitHilite&quot;&gt;V2O5&lt;/span&gt; cells comprising conventional &lt;span class=&quot;hitHilite&quot;&gt;porous&lt;/span&gt; &lt;span class=&quot;hitHilite&quot;&gt;separators&lt;/span&gt;.&lt;br /&gt;
	&amp;nbsp;&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">9</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;3.175&lt;/p&gt;
</style></custom4></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Vijayakumar, Vidyanand</style></author><author><style face="normal" font="default" size="100%">Diddens, Diddo</style></author><author><style face="normal" font="default" size="100%">Heuer, Andreas</style></author><author><style face="normal" font="default" size="100%">Kurungot, Sreekumar</style></author><author><style face="normal" font="default" size="100%">Winter, Martin</style></author><author><style face="normal" font="default" size="100%">Nair, Jijeesh Ravi</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Dioxolanone-anchored poly(allyl ether)-based cross-linked dual-salt polymer electrolytes for high-voltage lithium metal batteries</style></title><secondary-title><style face="normal" font="default" size="100%">ACS Applied Materials &amp; Interfaces</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">cross-linked polymer electrolyte</style></keyword><keyword><style  face="normal" font="default" size="100%">dual-salt electrolyte</style></keyword><keyword><style  face="normal" font="default" size="100%">high-voltage cathode</style></keyword><keyword><style  face="normal" font="default" size="100%">lithium metal battery</style></keyword><keyword><style  face="normal" font="default" size="100%">solvent-free photopolymerization</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2020</style></year><pub-dates><date><style  face="normal" font="default" size="100%">JAN </style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">12</style></volume><pages><style face="normal" font="default" size="100%">567-579</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;Novel cross-linked polymer electrolytes (XPEs) are synthesized by free-radical copolymerization induced by ultraviolet (UV)-light irradiation of a reactive solution, which is composed of a difunctional poly(ethylene glycol) diallyl ether oligomer (PEGDAE), a monofunctional reactive diluent 4-vinyl-1,3-dioxolan-2-one (VEC), and a stock solution containing lithium salt (lithium bis(trifluoromethanesulfonyl)imide, LiTFSI) in a carbonate-free nonvolatile plasticizer, poly(ethylene glycol) dimethyl ether (PEGDME). The resulting polymer matrix can be represented as a linear polyethylene chain functionalized with cyclic carbonate (dioxolanone) moieties and cross-linked by ethylene oxide units. A series of XPEs are prepared by varying the [O]/[Li] ratio (24 to 3) of the stock solution and thoroughly characterized using physicochemical (thermogravimetric analysis-mass spectrometry, differential scanning calorimetry, NMR, etc.) and electrochemical techniques. In addition, quantum chemical calculations are performed to elucidate the correlation between the electrochemical oxidation potential and the lithium ion-ethylene oxide coordination in the stock solution. Later, lithium bis(fluorosulfonyl)imide (LiFSI) salt is incorporated into the electrolyte system to produce a dual-salt XPE that exhibits improved electrochemical performance, a stable interface against lithium metal, and enhanced physical and chemical characteristics to be employed against high-voltage cathodes. The XPE membranes demonstrated excellent resistance against lithium dendrite growth even after reversibly plating and stripping lithium ions for more than 1000 h with a total capacity of 0.5 mAh cm(-2). Finally, the XPE films are assembled in a lab-scale lithium metal battery configuration by using carbon-coated LiFePO4 (LFP) or LiNi0.8Co0.15Al0.05O2 (NCA) as a cathode and galvanostatically cycled at 20, 40, and 60 degrees C. Remarkably, at 20 degrees C, the NCA-based lithium metal cells displayed excellent cycling stability and good capacity retention (&amp;gt;50%) even after 1000 cycles.&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">1</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;8.758&lt;/p&gt;
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