<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Bagwan, Farahanaz M.</style></author><author><style face="normal" font="default" size="100%">Dadkar, Sarthak S.</style></author><author><style face="normal" font="default" size="100%">Kinage, Anil K.</style></author><author><style face="normal" font="default" size="100%">Vasireddy, Satyam Naidu</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Reaction kinetics for dehydrogenation of decahydroquinoline to quinoline for hydrogen generation</style></title><secondary-title><style face="normal" font="default" size="100%">Chemical Engineering &amp; Technology</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Decahydroquinoline (DHQ)</style></keyword><keyword><style  face="normal" font="default" size="100%">degree of dehydrogenation</style></keyword><keyword><style  face="normal" font="default" size="100%">Dehydrogenation</style></keyword><keyword><style  face="normal" font="default" size="100%">rate-limiting step</style></keyword><keyword><style  face="normal" font="default" size="100%">Reaction kinetics</style></keyword><keyword><style  face="normal" font="default" size="100%">Weisz-Prater criterion</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2026</style></year><pub-dates><date><style  face="normal" font="default" size="100%">FEB</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">49</style></volume><pages><style face="normal" font="default" size="100%">e70177</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Catalytic dehydrogenation of decahydroquinoline (DHQ) to quinoline is a promising pathway for hydrogen release in liquid organic hydrogen carrier systems. In this work, solvent-free DHQ dehydrogenation over Pd/Al2O3 is systematically investigated to evaluate hydrogen release performance and reaction kinetics. High DHQ conversion (83.9%) and degree of dehydrogenation (82.7%) are achieved at optimal reaction conditions. A power-law kinetic model based on a simplified reaction mechanism is developed and simulated using a Markov Chain Monte Carlo (MCMC) approach for estimation of rate constants and validation of concentration profiles with experimental data. The apparent activation energies are determined to be 45.85 kJ/mol for DHQ to 5,6,7,8-tetrahydroquinoline (bz-THQ) and 185.43 kJ/mol for bz-THQ to quinoline formation, identifying latter as the rate-limiting step. This framework provides mechanistic insight and supports the potential of DHQ as an efficient hydrogen carrier.&lt;/p&gt;
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	Foreign&lt;/p&gt;
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	1.6&lt;/p&gt;
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