<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kumar Das, Deep</style></author><author><style face="normal" font="default" size="100%">Marayathungal, Jumana Hasin</style></author><author><style face="normal" font="default" size="100%">Palakkolil, Athira</style></author><author><style face="normal" font="default" size="100%">Sarma, Dhritismita</style></author><author><style face="normal" font="default" size="100%">Khan, Akram Aadil</style></author><author><style face="normal" font="default" size="100%">Kumar, M. Praveen</style></author><author><style face="normal" font="default" size="100%">Kudlu, Ashwath</style></author><author><style face="normal" font="default" size="100%">Choudhary, Mahendra</style></author><author><style face="normal" font="default" size="100%">Hathwar, Venkatesha R.</style></author><author><style face="normal" font="default" size="100%">Pujala, Ravi Kumar</style></author><author><style face="normal" font="default" size="100%">Mahata, Arup</style></author><author><style face="normal" font="default" size="100%">Kundu, Janardan</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Supercooled liquid phases of luminescent zero dimensional metal halide hybrids</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Physical Chemistry Letters</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">16</style></volume><pages><style face="normal" font="default" size="100%">9391-9400</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Chemical design of metal halide hybrids (MHHs) with suppressed melting point (T-m) allows access to glassy phases from their liquid-melts. Thermal phase change (crystal-melt-glass) properties of glassy MHHs (with glass transition temperature T-g &amp;gt; room temperature) have been exploited for device applications. However, room temperature stable supercooled liquid (SCL) MHHs (with T-g &amp;lt; room temperature), originating from glass-SCL phase change, remain inaccessible. Here, a molecular design strategy is reported to access ambient stable, melt-processable, SCL multimetallic bromide hybrids (Mn2+,Cd2+; Mn2+,Zn2+; Benzyltributylammonium) with low T-g (15-16 degrees C), low T-m (90-100 degrees C), green luminescence, and high optical transparency. Structural, optical, thermal, and computational analyses highlight chemical design principles and support dopant (Mn2+) based luminescence. Rheological measurements confirm the SCL phase that shows thermal hysteresis and estimate relaxation time scales. This work provides a new material platform showcasing enhanced melt-processability for fabrication of moldable devices, unravelling chemical makeup-property correlation and expanding the material phase types of MHHs.&lt;/p&gt;
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