<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Nuralieva, Guzal</style></author><author><style face="normal" font="default" size="100%">Umirzakova, Oydinoy</style></author><author><style face="normal" font="default" size="100%">Torambetov, Batirbay</style></author><author><style face="normal" font="default" size="100%">Rasulov, Abdusamat</style></author><author><style face="normal" font="default" size="100%">Ashurov, Jamshid</style></author><author><style face="normal" font="default" size="100%">Kadirova, Shakhnoza</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synthesis, crystal structure and Hirshfeld analysis of a novel supra­molecular compound [Co(tsc)3]2[Co(cit)2](NO3)4·4H2O</style></title><secondary-title><style face="normal" font="default" size="100%">Acta Crystallographica Section E-Crystallographic Communications</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">MAR</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">81</style></volume><pages><style face="normal" font="default" size="100%">248-251</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;A new cobalt complex, bis­[tris­(amino­thio­urea)cobalt(III)] bis­[2-(carb­oxy­methyl)-2-hy­droxy­butane­dioato]cobalt(II) tetra­nitrate tetra­hydrate, [Co(CH&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;5&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;N&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;S)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;][Co(C&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;6&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;H&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;6&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;O&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;7&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;]&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;0.5&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;(NO&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;·2H&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;O, designated as [Co(tsc)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;]&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;[Co(cit)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;](NO&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;3&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;)&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;4&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;·4H&lt;/span&gt;&lt;span class=&quot;inf&quot; style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&lt;span style=&quot;font-size: 9px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em;&quot;&gt;2&lt;/span&gt;&lt;/span&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;O, was synthesized. Two crystallographically independent cobalt centers are present. In the first, the central metal atom is chelated by three thio­semicarbazide ligands in a bidentate fashion whereas the second, positioned on a crystallographic inversion center, is hexa­coordinated by two citrate anions in a distorted octa­hedral geometry. Additionally, two water mol­ecules and two nitrate anions are present in the&amp;nbsp;&lt;/span&gt;&lt;a class=&quot;ref_lookup_yellow hideyellow&quot; href=&quot;https://dictionary.iucr.org/Asymmetric_unit&quot; style=&quot;text-decoration-line: none; color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot; target=&quot;Navigator&quot;&gt;asymmetric unit.&lt;/a&gt;&lt;span style=&quot;color: rgb(0, 0, 0); font-family: Verdana, Arial, Helvetica, sans-serif;&quot;&gt;&amp;nbsp;Hirshfeld surface analysis revealed that the presence of numerous donor and acceptor groups in the complex, which facilitate hydrogen-bonding inter­actions that contribute significantly to the overall cohesion of the crystal structure.&lt;/span&gt;&lt;/p&gt;
</style></abstract><issue><style face="normal" font="default" size="100%">3</style></issue><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3></record><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Nuralieva, Guzal</style></author><author><style face="normal" font="default" size="100%">Alieva, Mushtariy</style></author><author><style face="normal" font="default" size="100%">Torambetov, Batirbay</style></author><author><style face="normal" font="default" size="100%">Leslee, Denzil Britto Christopher</style></author><author><style face="normal" font="default" size="100%">Senthilkumar, Beeran</style></author><author><style face="normal" font="default" size="100%">Kaur, Simranjeet</style></author><author><style face="normal" font="default" size="100%">Dabke, Niteen B.</style></author><author><style face="normal" font="default" size="100%">Vanka, Kumar</style></author><author><style face="normal" font="default" size="100%">Ashurov, Jamshid</style></author><author><style face="normal" font="default" size="100%">Kadirova, Shakhnoza</style></author><author><style face="normal" font="default" size="100%">Gonnade, Rajesh G.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Synthesis, crystal structure, DFT calculation and catalytic activity of a polymer complex of zinc(II) succinate with 2-amino-1,3,4-thiadiazole</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Molecular Structure</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">DFT</style></keyword><keyword><style  face="normal" font="default" size="100%">Dihydropyrimidinones</style></keyword><keyword><style  face="normal" font="default" size="100%">Polymer complex</style></keyword><keyword><style  face="normal" font="default" size="100%">succinate</style></keyword><keyword><style  face="normal" font="default" size="100%">Thiadiazole</style></keyword><keyword><style  face="normal" font="default" size="100%">zinc</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">AUG</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">1338</style></volume><pages><style face="normal" font="default" size="100%">142274</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	A polymer complex of zinc(II) succinate with a 2-amino-1,3,4-thiadialole ligand, denoted as [Zn2L2(suc)2]n, was synthesized and characterized by NMR, ESI-MS, FTIR, and FT-Raman spectroscopy, TGA, and X-ray crystallography. The polymer complex crystallizes in the orthorhombic noncentrosymmetric Pna21 space group and features a five-coordinate zinc ion in a distorted spherical square pyramidal geometry. The Hirshfeld surface analysis was carried out to evaluate the intermolecular interactions. Additionally, computational studies were also conducted to assess the stability of the Zn polymer complex and analyze the electron density distribution of the HOMO and LUMO. The catalytic activity of our complex was tested, interestingly, that showed good results for Biginelli reactions with distinct substrate scope in good to high yield at mild reaction conditions.&lt;/p&gt;
</style></abstract><work-type><style face="normal" font="default" size="100%">Article</style></work-type><custom3><style face="normal" font="default" size="100%">&lt;p&gt;
	Foreign&lt;/p&gt;
</style></custom3><custom4><style face="normal" font="default" size="100%">&lt;p&gt;
	4.0&lt;/p&gt;
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