<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kotwal, Mehejabeen</style></author><author><style face="normal" font="default" size="100%">Kumar, Anuj</style></author><author><style face="normal" font="default" size="100%">Darbha, Srinivas</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Three-dimensional, mesoporous titanosilicates as catalysts for producing biodiesel and biolubricants</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Molecular Catalysis A-Chemical</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Biodiesel</style></keyword><keyword><style  face="normal" font="default" size="100%">Esterification of fatty acid</style></keyword><keyword><style  face="normal" font="default" size="100%">Lubricant basestocks</style></keyword><keyword><style  face="normal" font="default" size="100%">mesoporous materials</style></keyword><keyword><style  face="normal" font="default" size="100%">Ti-SBA-12</style></keyword><keyword><style  face="normal" font="default" size="100%">Ti-SBA-16</style></keyword><keyword><style  face="normal" font="default" size="100%">Titanosilicates</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2013</style></year><pub-dates><date><style  face="normal" font="default" size="100%">OCT</style></date></pub-dates></dates><publisher><style face="normal" font="default" size="100%">ELSEVIER SCIENCE BV</style></publisher><pub-location><style face="normal" font="default" size="100%">PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS</style></pub-location><volume><style face="normal" font="default" size="100%">377</style></volume><pages><style face="normal" font="default" size="100%">65-73</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The application of three-dimensional, mesoporous titanosilicates, Ti-SBA-12 and Ti-SBA-16, as reusable solid acid catalysts for producing biodiesel and biolubricants is reported for the first time. Biodiesel was prepared by esterification of oleic acid with monohydric methanol and biolubricants by esterification with polyhydric alcohols (glycerol, trimethylolpropane, neopentyl glycol and pentaerythritol). High catalytic activity of these catalysts is attributed to the presence of dispersed Lewis acidic Ti sites and mesoporosity in the structure. Biodiesel yields as high as 90 mol% were obtained at 443 K. Surface hydrophobicity of the catalyst has also a predominant role, especially, in reactions involving polyhydric alcohols. In those reactions, Ti-SBA-16 showed higher catalytic activity than Ti-SBA-12. (c) 2013 Elsevier B.V. All rights reserved.&lt;/p&gt;</style></abstract><custom3><style face="normal" font="default" size="100%">Foreign</style></custom3><custom4><style face="normal" font="default" size="100%">3.679
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