<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="7.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Ajithkumar, V. S.</style></author><author><style face="normal" font="default" size="100%">Khilari, Nripen</style></author><author><style face="normal" font="default" size="100%">Ghanwat, Pratiksha B.</style></author><author><style face="normal" font="default" size="100%">Koley, Debasis</style></author><author><style face="normal" font="default" size="100%">Sen, Sakya S.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">C=C insertion over N=C=O of allyl isocyanate into the Ge-Si bond of a germylene</style></title><secondary-title><style face="normal" font="default" size="100%">European Journal of Inorganic Chemistry</style></secondary-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">Cyclotrimerization</style></keyword><keyword><style  face="normal" font="default" size="100%">Density functional theory</style></keyword><keyword><style  face="normal" font="default" size="100%">Germylene</style></keyword><keyword><style  face="normal" font="default" size="100%">Insertion</style></keyword><keyword><style  face="normal" font="default" size="100%">isocyanates</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2025</style></year><pub-dates><date><style  face="normal" font="default" size="100%">SEP</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">28</style></volume><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;
	Two isocyanates are reacted with the germylene, PhC(NtBu)(2)Ge-Si(SiMe3)(3) (1). Phenyl isocyanate undergoes catalytic cyclotrimerization with 1 leading to 1,3,5-triphenyl isocyanurate (2), while allyl isocyanate undergoes both cyclotrimerization and the C=C bond insertion between the Ge-Si bond. The constitution of 3 is determined by single-crystal X-ray studies. The contrasting reactivity pattern is explained by comprehensive density functional theory studies.&lt;/p&gt;
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	Foreign&lt;/p&gt;
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	2&lt;/p&gt;
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